Electrodeposition of Ni–Co–Fe mixed sulfide ultrathin nanosheets on Ni nanocones: a low-cost, durable and high performance catalyst for electrochemical water splitting

Nanoscale ◽  
2019 ◽  
Vol 11 (35) ◽  
pp. 16621-16634 ◽  
Author(s):  
Ghasem Barati Darband ◽  
Mahmood Aliofkhazraei ◽  
Suyeon Hyun ◽  
Alireza Sabour Rouhaghdam ◽  
Sangaraju Shanmugam

Ni–Co–Fe mixed sulfide ultrathin nanosheets obtained by electrodeposition method exhibits excellent electrocatalytic activity. The Ni–Co–Fe nanosheets require the overpotential of 106 and 207 mV to generate 10 mA cm−2 current density for the HER, and OER, respectively.

Author(s):  
Sheng-Hao Cai ◽  
Xiao-Nan Chen ◽  
Meng-Jie Huang ◽  
Ji-Yuan Han ◽  
Yu-Wei Zhou ◽  
...  

Exploiting high-performance, low-cost, and robust bifunctional catalysts toward electrochemical water splitting is of great importance, but remains challenging. Herein, a novel hybrid electrocatalyst of Ni-Fe-Ru-based phosphide heterostructures directly grown on...


Nanoscale ◽  
2021 ◽  
Author(s):  
Haibin Ma ◽  
ChangNing SUN ◽  
Zhili Wang ◽  
Qing Jiang

It is of great importance to develop efficient and low-cost oxygen evolution reaction (OER) electrocatalysts for electrochemical water splitting. Herein, S doped NiCoVOx nanosheets grown on Ni-Foam (S-NiCoVOx/NF) with modified...


2019 ◽  
Vol 10 ◽  
pp. 281-293 ◽  
Author(s):  
Donghui Zheng ◽  
Man Li ◽  
Yongyan Li ◽  
Chunling Qin ◽  
Yichao Wang ◽  
...  

Developing a facile and environmentally friendly approach to the synthesis of nanostructured Ni(OH)2 electrodes for high-performance supercapacitor applications is a great challenge. In this work, we report an extremely simple route to prepare a Ni(OH)2 nanopetals network by immersing Ni nanofoam in water. A binder-free composite electrode, consisting of Ni(OH)2 nanopetals network, Ni nanofoam interlayer and Ni-based metallic glass matrix (Ni(OH)2/Ni-NF/MG) with sandwich structure and good flexibility, was designed and finally achieved. Microstructure and morphology of the Ni(OH)2 nanopetals were characterized. It is found that the Ni(OH)2 nanopetals interweave with each other and grow vertically on the surface of Ni nanofoam to form an “ion reservoir”, which facilitates the ion diffusion in the electrode reaction. Electrochemical measurements show that the Ni(OH)2/Ni-NF/MG electrode, after immersion in water for seven days, reveals a high volumetric capacitance of 966.4 F/cm3 at a current density of 0.5 A/cm3. The electrode immersed for five days exhibits an excellent cycling stability (83.7% of the initial capacity after 3000 cycles at a current density of 1 A/cm3). Furthermore, symmetric supercapacitor (SC) devices were assembled using ribbons immersed for seven days and showed a maximum volumetric energy density of ca. 32.7 mWh/cm3 at a power density of 0.8 W/cm3, and of 13.7 mWh/cm3 when the power density was increased to 2 W/cm3. The fully charged SC devices could light up a red LED. The work provides a new idea for the synthesis of nanostructured Ni(OH)2 by a simple approach and ultra-low cost, which largely extends the prospect of commercial application in flexible or wearable devices.


2018 ◽  
Vol 10 (47) ◽  
pp. 40568-40576 ◽  
Author(s):  
Juan Jian ◽  
Long Yuan ◽  
Hui Qi ◽  
Xuejiao Sun ◽  
Le Zhang ◽  
...  

2020 ◽  
Vol 13 (1) ◽  
pp. 102-110 ◽  
Author(s):  
Weiju Hao ◽  
Renbing Wu ◽  
Hao Huang ◽  
Xin Ou ◽  
Lincai Wang ◽  
...  

A family of catalytic electrodes fabricated by insulating substrates of paper, cloth and sponge which bring dramatic advantages of high performance, low cost, light weight, eco-friendliness, flexibility, and simple fabrication, were developed.


2017 ◽  
Vol 5 (17) ◽  
pp. 7769-7775 ◽  
Author(s):  
Xiuhui Sun ◽  
Qi Shao ◽  
Yecan Pi ◽  
Jun Guo ◽  
Xiaoqing Huang

A general approach to ultrathin NiM (M = Fe, Co, Mn) hydroxide nanosheets as efficient electrocatalysts for overall water splitting.


2014 ◽  
Vol 24 (21) ◽  
pp. 3123-3129 ◽  
Author(s):  
Ksenia Fominykh ◽  
Johann M. Feckl ◽  
Johannes Sicklinger ◽  
Markus Döblinger ◽  
Sebastian Böcklein ◽  
...  

2021 ◽  
Vol 8 ◽  
Author(s):  
Junfeng Li ◽  
Xianzi Zhou ◽  
Kai Lu ◽  
Chao Ma ◽  
Liang Li ◽  
...  

Molybdenum sulfide (MoS2) has become a potential anode of lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to its high theoretical capacity and low cost. However, the volume expansion, poor electrical conductivity and dissolution of polysulfides in the electrolyte during the cycling process severely limited its applications. Herein, few-layered MoS2@N-doped carbon (F-MoS2@NC) was synthesized through a facile solvothermal and annealing process. It was found that the addition of N-doped carbon precursor could significantly promote the formation of few-layered MoS2 and improve the performances of lithium and sodium storage. A high reversible capacity of 482.6 mA h g−1 at a high current density of 2000 mA g−1 could be obtained for LIBs. When used as anode material for SIBs, F-MoS2@NC hybrids could maintain a reversible capacity of 171 mA h g−1 at a high current density of 1,000 mA g−1 after 600 cycles. This work should provide new insights into carbon hybrid anode materials for both LIBs and SIBs.


Nanoscale ◽  
2019 ◽  
Vol 11 (48) ◽  
pp. 23318-23329 ◽  
Author(s):  
Lina Jia ◽  
Chen Li ◽  
Yaru Zhao ◽  
Bitao Liu ◽  
Shixiu Cao ◽  
...  

Non-precious metal-based electrocatalysts with high activity and stability for efficient hydrogen evolution reactions are of critical importance for low-cost and large-scale water splitting.


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