scholarly journals Hydrogen bond assisted photoinduced intramolecular electron transfer and proton coupled electron transfer in an ultrafast time domain using a ruthenium-anthraquinone dyad

2019 ◽  
Vol 18 (10) ◽  
pp. 2430-2441 ◽  
Author(s):  
Ananta Dey ◽  
Jayanta Dana ◽  
Sunil Aute ◽  
Amitava Das ◽  
Hirendra N. Ghosh

PCET kinetics for the formation of charge-separated states was explored by using femtosecond transient absorption spectroscopy. Hydrogen bonding between water and the reduced anthraquinone accounted for thermodynamic and kinetic stabilization.

Author(s):  
Junjie Chen ◽  
Sen Guo ◽  
Dabin Lin ◽  
Zhaogang Nie ◽  
Chung-Che Huang ◽  
...  

Femtosecond transient absorption spectroscopy has been employed to unravel separate initial nonequilibrium dynamic process of photo-injected electrons and holes during the formation process of the lowest excitons at the K-valley...


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