Recent development of brush polymers via polymerization of poly(ethylene glycol)-based macromonomers

2019 ◽  
Vol 10 (18) ◽  
pp. 2212-2222 ◽  
Author(s):  
Xiaojin Zhang ◽  
Yu Dai

Polymerization of poly(ethylene glycol)-based macromonomers is a facile and versatile synthetic method to generate well-defined brush polymers.

RSC Advances ◽  
2020 ◽  
Vol 10 (48) ◽  
pp. 28680-28694 ◽  
Author(s):  
Zhihui Yang ◽  
Guangfeng Wu

A synthetic method was developed to prepare biodegradable waterborne polyurethanes (BHPUs) with a high solid content by introducing different molecular weights of poly(ethylene glycol) (PEG) into poly(ε-caprolactone) (PCL)-based polyurethanes.


2012 ◽  
Vol 46 (1) ◽  
pp. 63-71 ◽  
Author(s):  
Olga Yu. Zolotarskaya ◽  
Quan Yuan ◽  
Kenneth J. Wynne ◽  
Hu Yang

Synlett ◽  
2008 ◽  
Vol 2008 (8) ◽  
pp. 1230-1232 ◽  
Author(s):  
Miloš Sedlák ◽  
Pavel Drabina ◽  
Markéta Svobodová ◽  
Jiří Hanusek

Molecules ◽  
2021 ◽  
Vol 26 (16) ◽  
pp. 4802
Author(s):  
Adrien Lusterio ◽  
Michael A. Brook

Silicone surfactants are widely used in many industries and mostly rely on poly(ethylene glycol) (PEG) as the hydrophile. This can be disadvantageous because commercial PEG examples vary significantly in polydispersity—constraining control over surface activity of the surfactant—and there are environmental concerns associated with PEG. Herein, we report a three-step synthetic method for the preparation of saccharide-silicone surfactants using the natural linker, cysteamine, and saccharide lactones. The Piers–Rubinsztajn plus thiol-ene plus amidation process is attractive for several reasons: if employed in the correct synthetic order, it allows for precise tailoring of both hydrophobe and hydrophile; it permits the ready utilization of natural hydrophiles cysteamine and saccharides in combination with silicones, which have significantly better environmental profiles than PEG; and the products exhibit interesting surface activities.


2019 ◽  
Vol 10 (10) ◽  
Author(s):  
Anton Bonartsev ◽  
Vera Voinova ◽  
Elizaveta Akoulina ◽  
Andrey Dudun ◽  
Irina Zharkova ◽  
...  

2007 ◽  
Vol 32 (5) ◽  
pp. 431-446 ◽  
Author(s):  
Tahar Bartil ◽  
Mahmoud Bounekhel ◽  
Cedric Calberg ◽  
Robert Jerome

2019 ◽  
Author(s):  
Alex Khang ◽  
Andrea Gonzalez Rodriguez ◽  
Megan E. Schroeder ◽  
Jacob Sansom ◽  
Emma Lejeune ◽  
...  

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