Simple Lewis pairs of zinc salts and organobases as bifunctional catalysts for controlled ring-opening polymerization of O-carboxyanhydrides

2019 ◽  
Vol 10 (40) ◽  
pp. 5498-5506 ◽  
Author(s):  
Pei Wang ◽  
Jinpeng Liang ◽  
Ting Yin ◽  
Jing Yang
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Bifunctional Catalysis ◽  
Bifunctional Catalysts ◽  
Hydroxyalkanoic Acid ◽  
Zinc Salts ◽  
Lewis Pairs

Simple Lewis pairs consisting of organobases and zinc salts were explored to promote ring-opening polymerization of phenyl O-carboxyanhydride via bifunctional catalysis, producing well-defined poly(α-hydroxyalkanoic acid)s with good isotacticity (Pm = 0.88).

Insights into the mechanism for ring-opening polymerization of lactide catalyzed by Zn(C6F5)2/organic superbase Lewis pairs

2016 ◽  
Vol 6 (21) ◽  
pp. 7763-7772 ◽  
Author(s):  
Xiao-Qing Li ◽  
Bin Wang ◽  
He-Yuan Ji ◽  
Yue-Sheng Li
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Experimental Results ◽  
Maldi Tof Ms ◽  
Maldi Tof ◽  
Good Consistency ◽  
Plausible Mechanism ◽  
Tof Ms ◽  
Lewis Pairs

A plausible mechanism for ring-opening polymerization of lactide catalyzed by Zn(C6F5)2-based Lewis pairs was proposed based on in situ NMR and MALDI-TOF MS analyses. Several experimental results show very good consistency with the proposed mechanism.

Computational Investigation of Mechanisms for Ring-Opening Polymerization of ε-Caprolactone:  Evidence for Bifunctional Catalysis by Alcohols

2006 ◽  
Vol 3 (1) ◽  
pp. 146-155 ◽  
Author(s):  
Nicholas Buis ◽  
Samuel A. French ◽  
Giuseppe D. Ruggiero ◽  
Bruno Stengel ◽  
Arran A. D. Tulloch ◽  
...  
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Bifunctional Catalysis ◽  
Computational Investigation

Controlled ring-opening polymerization ofl-lactide and ε-caprolactone catalyzed by aluminum-based Lewis pairs or Lewis acid alone

2016 ◽  
Vol 55 (2) ◽  
pp. 297-303 ◽  
Author(s):  
Yuushou Nakayama ◽  
Shunsuke Kosaka ◽  
Kentaro Yamaguchi ◽  
Gentaro Yamazaki ◽  
Ryo Tanaka ◽  
...  
Keyword(s):  
Lewis Acid ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Lewis Pairs

Near-to-eutectic mixtures as bifunctional catalysts in the low-temperature-ring-opening-polymerization of ε-caprolactone

2015 ◽  
Vol 17 (6) ◽  
pp. 3632-3643 ◽  
Author(s):  
Sara García-Argüelles ◽  
Carolina García ◽  
María C. Serrano ◽  
María C. Gutiérrez ◽  
M. Luisa Ferrer ◽  
...  
Keyword(s):  
Low Temperature ◽  
Ring Opening ◽  
Methanesulfonic Acid ◽  
Ring Opening Polymerization ◽  
Bifunctional Catalysts ◽  
Eutectic Mixtures

We have investigated the ring-opening polymerization (ROP) of ε-caprolactone using mixtures of methanesulfonic acid and the guanidine 1,5,7-triazabicyclo[4.4.0]dec-5-ene as the catalyst.

Controlled ring-opening polymerization of α-amino acid N-carboxy-anhydride by frustrated amine/borane Lewis pairs

2017 ◽  
Vol 53 (37) ◽  
pp. 5155-5158 ◽  
Author(s):  
Hongyuan Zhang ◽  
Yanzhao Nie ◽  
Xinmei Zhi ◽  
Haifeng Du ◽  
Jing Yang
Keyword(s):  
Amino Acid ◽  
Lewis Acid ◽  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Amine Groups ◽  
Lewis Pairs

An FLP intermediate formed through the bulky borane Lewis acid and the amine groups of the propagation chain end controlled the ring-opening polymerization of α-amino acid N-carboxy-anhydride monomers.

Catalytic insights into acid/base conjugates: highly selective bifunctional catalysts for the ring-opening polymerization of lactide

2011 ◽  
Vol 47 (11) ◽  
pp. 3105 ◽  
Author(s):  
Daniel J. Coady ◽  
Kazuki Fukushima ◽  
Hans W. Horn ◽  
Julia E. Rice ◽  
James L. Hedrick
Keyword(s):  
Ring Opening ◽  
Ring Opening Polymerization ◽  
Bifunctional Catalysts ◽  
Acid Base
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