Recoverable and recyclable nickel–cobalt magnetic alloy nanoparticle catalyzed reversible deactivation radical polymerization of methyl methacrylate at 25 °C

2020 ◽  
Vol 11 (2) ◽  
pp. 287-291 ◽  
Author(s):  
Sk Arif Mohammad ◽  
Shashikant Shingdilwar ◽  
Sanjib Banerjee
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Magnetic Alloy ◽  
Poly Methyl Methacrylate ◽  
Nickel Cobalt ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

Recyclable Ni–Co alloy catalyzed synthesis of well-defined poly(methyl methacrylate) (PMMA, up to 129 500 g mol−1) with narrow-dispersity (Đ = 1.30) via a reversible deactivation radical polymerization technique is reported.

Hexamethylphosphoramide as a highly reactive catalyst for the reversible-deactivation radical polymerization of MMA with an in situ formed alkyl iodide initiator

2017 ◽  
Vol 8 (39) ◽  
pp. 6073-6085 ◽  
Author(s):  
Yan-an Wang ◽  
Yan Shi ◽  
Zhifeng Fu ◽  
Wantai Yang
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Alkyl Iodide ◽  
Highly Efficient ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization ◽  
Organic Catalyst

A novel and highly efficient organic catalyst for the reversible-deactivation radical polymerization (RDRP) of methyl methacrylate with anin situformed alkyl iodide initiator.

Ligand effect and oxygen tolerance studies in photochemically induced copper mediated reversible deactivation radical polymerization of methyl methacrylate in dimethyl sulfoxide

2015 ◽  
Vol 6 (13) ◽  
pp. 2523-2530 ◽  
Author(s):  
J. Mosnáček ◽  
A. Eckstein-Andicsová ◽  
K. Borská
Keyword(s):  
Methyl Methacrylate ◽  
Dimethyl Sulfoxide ◽  
Radical Polymerization ◽  
Ligand Effect ◽  
Oxygen Tolerance ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

Well-defined PMMA can be prepared using photoRDRP without the necessity of degassing of MMA and/or DMSO.

scholarly journals Reversible-Deactivation Radical Polymerization of Methyl Methacrylate and Styrene Mediated by Alkyl Dithiocarbamates and Copper Acetylacetonates

2013 ◽  
Vol 46 (14) ◽  
pp. 5512-5519 ◽  
Author(s):  
Yaozhong Zhang ◽  
Kristin Schröder ◽  
Yungwan Kwak ◽  
Pawel Krys ◽  
Aurélie N. Morin ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

Bis(formylpyrrolyl) cobalt complexes as mediators in the reversible-deactivation radical polymerization of styrene and methyl methacrylate

2018 ◽  
Vol 42 (8) ◽  
pp. 5900-5913 ◽  
Author(s):  
Tiago F. C. Cruz ◽  
Pedro M. M. Machado ◽  
Clara S. B. Gomes ◽  
José R. Ascenso ◽  
M. Amélia N. D. A. Lemos ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Radical Polymerization ◽  
Cobalt Complexes ◽  
Reversible Deactivation ◽  
Reversible Deactivation Radical Polymerization

Bis(formylpyrrolyl) cobalt complexes mediate the reversible-deactivation radical polymerization of styrene and methyl methacrylate.

Photocontrolled iodine-mediated reversible-deactivation radical polymerization with a semifluorinated alternating copolymer as the macroinitiator

2020 ◽  
Vol 11 (47) ◽  
pp. 7497-7505
Author(s):  
Jiannan Cheng ◽  
Kai Tu ◽  
Enjie He ◽  
Jinying Wang ◽  
Lifen Zhang ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Radical Polymerization ◽  
Room Temperature ◽  
Blue Led ◽  
Led Light ◽  
Alternating Copolymers ◽  
Alternating Copolymer ◽  
Reversible Deactivation ◽  
Novel Strategy ◽  
Reversible Deactivation Radical Polymerization

A novel strategy for preparing block copolymers with semifluorinated alternating copolymers as macroinitiators was established by photocontrolled iodine-mediated RDRP under irradiation with blue LED light at room temperature.

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