A denitrogenative palladium-catalyzed cascade for regioselective synthesis of fluorenes

Hydrazone assists Pd(ii)/(iv) oxidative addition and is the methylene synthon in a palladium-catalyzed, norbornene-mediated regioselective synthesis of fluorenes.

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ChemInform Abstract: Retention of Configuration on the Oxidative Addition of P-H Bond to Platinum(0) Complexes: The First Straightforward Synthesis of Enantiomerically Pure P-Chiral Alkenylphosphinates via Palladium-Catalyzed Stereospecific Hydrophosphiny

ChemInform ◽

10.1002/chin.200235159 ◽

2010 ◽

Vol 33 (35) ◽

pp. no-no

Author(s):

Li-Biao Han ◽

Chang-Qiu Zhao ◽

Shun-ya Onozawa ◽

Midori Goto ◽

Masato Tanaka

Keyword(s):

Oxidative Addition ◽

Enantiomerically Pure ◽

Palladium Catalyzed

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Palladium-Catalyzed Isobenzofuran Generation under Neutral Conditions via Oxidative Addition to Lactol Methyl Ether

Organic Letters ◽

10.1021/ol0265416 ◽

2002 ◽

Vol 4 (20) ◽

pp. 3355-3357 ◽

Cited By ~ 28

Author(s):

Koichi Mikami ◽

Hirofumi Ohmura

Keyword(s):

Methyl Ether ◽

Oxidative Addition ◽

Palladium Catalyzed ◽

Neutral Conditions

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Palladium-catalyzed regioselective synthesis of benzosultams from functionalized ynamides and benzotriazoles/tetrazoles

Tetrahedron ◽

10.1016/j.tet.2017.03.070 ◽

2017 ◽

Vol 73 (19) ◽

pp. 2766-2773 ◽

Cited By ~ 9

Author(s):

Alla Siva Reddy ◽

A. Leela Siva Kumari ◽

K.C. Kumara Swamy

Keyword(s):

Regioselective Synthesis ◽

Palladium Catalyzed

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Ligand-Controlled Palladium-Catalyzed Alkoxycarbonylation of Allenes: Regioselective Synthesis of α,β- and β,γ-Unsaturated Esters

Journal of the American Chemical Society ◽

10.1021/jacs.5b04052 ◽

2015 ◽

Vol 137 (26) ◽

pp. 8556-8563 ◽

Cited By ~ 57

Author(s):

Jie Liu ◽

Qiang Liu ◽

Robert Franke ◽

Ralf Jackstell ◽

Matthias Beller

Keyword(s):

Regioselective Synthesis ◽

Unsaturated Esters ◽

Palladium Catalyzed

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Palladium-Catalyzed Regioselective Synthesis of 3-Arylindoles from N -Ts-Anilines and Styrenes

Angewandte Chemie International Edition ◽

10.1002/anie.201702205 ◽

2017 ◽

Vol 56 (23) ◽

pp. 6636-6640 ◽

Cited By ~ 27

Author(s):

So Won Youn ◽

Tae Yun Ko ◽

Young Ho Jang

Keyword(s):

Regioselective Synthesis ◽

Palladium Catalyzed

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Thiolate–palladium(iv) or sulfonium–palladate(0)? A theoretical study on the mechanism of palladium-catalyzed C–S bond formation reactions

Organic Chemistry Frontiers ◽

10.1039/c6qo00841k ◽

2017 ◽

Vol 4 (6) ◽

pp. 943-950 ◽

Cited By ~ 9

Author(s):

Dongdong Xu ◽

Xiaotian Qi ◽

Meng Duan ◽

Zhaoyuan Yu ◽

Lei Zhu ◽

...

Keyword(s):

Theoretical Study ◽

Bond Formation ◽

Oxidative Addition ◽

Palladium Catalyzed ◽

Catalytic Cycles ◽

Bond Formation Reactions

Thiolate–palladium(iv) intermediates are generated through oxidative addition in our suggested mechanisms, and are the key intermediates in these catalytic cycles.

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