Novel structurally-stable Na-rich Na4V2O7 cathode material with high reversible capacity by utilization of anion redox activity

2020 ◽  
Vol 56 (59) ◽  
pp. 8245-8248 ◽  
Author(s):  
Bizhe Su ◽  
Hanqin Liang ◽  
Junnan Liu ◽  
Jimmy Wu ◽  
Neeraj Sharma ◽  
...  

A sodium-rich vanadium compound, Na4V2O7, is investigated as a cathode material for sodium-ion batteries, with a high reversible capacity of 194 mA h g−1 after activating to 4.7 V.

2021 ◽  
Author(s):  
Jiaying Liao ◽  
Jingchen Han ◽  
Jianzhi Xu ◽  
Yichen Du ◽  
Yingying Sun ◽  
...  

We demonstrate an economical polytetrafluoroethylene-assisted fluorination method to synthesize three binary sodium-rich fluorides Na2MVF7 (M = Mn, Fe, and Co). The optimal Na2FeVF7 cathode delivers a high reversible capacity of...


2018 ◽  
Vol 6 (36) ◽  
pp. 17437-17443 ◽  
Author(s):  
Jonghyun Choi ◽  
Won-Sik Kim ◽  
Kyeong-Ho Kim ◽  
Seong-Hyeon Hong

Tin phosphide (Sn4P3) has emerged as an anode for sodium ion batteries (SIBs) due to its high reversible capacity and low redox potential.


2016 ◽  
Vol 4 (44) ◽  
pp. 17419-17430 ◽  
Author(s):  
Ramchandra S. Kalubarme ◽  
Akbar I. Inamdar ◽  
D. S. Bhange ◽  
Hyunsik Im ◽  
Suresh W. Gosavi ◽  
...  

This is the first report on the use of metal titanate (NiTiO3), in the form of ultrafine nanoparticles, as an anode material for Na-ion rechargeable batteries. NiTiO3 was prepared using a simple and economical hydrothermal process, and the ultrafine nanoparticles exhibited a high reversible capacity and an excellent cycling performance.


2015 ◽  
Vol 8 (12) ◽  
pp. 3531-3538 ◽  
Author(s):  
Jun Liu ◽  
Peter Kopold ◽  
Chao Wu ◽  
Peter A. van Aken ◽  
Joachim Maier ◽  
...  

Uniform yolk–shell Sn4P3@C nanospheres exhibit very high reversible capacity, superior rate capability and stable cycling performance for Na-ion batteries.


2020 ◽  
Vol 12 (9) ◽  
pp. 1429-1432
Author(s):  
Seunghwan Cha ◽  
Changhyeon Kim ◽  
Huihun Kim ◽  
Gyu-Bong Cho ◽  
Kwon-Koo Cho ◽  
...  

Recently, sodium ion batteries have attracted considerable interest for large-scale electric energy storage as an alternative to lithium ion batteries. However, the development of anode materials with long cycle life, high rate, and high reversible capacity is necessary for the advancement of sodium ion batteries. Bi anode is a promising candidate for sodium ion batteries due to its high theoretical capacity (385 mAh g–1 or 3800 mAh l–1) and high electrical conductivity (7.7 × 105 S m –1). Herein, we report the preparation of Bi anode using micro-sized commercial Bi particles. DME-based electrolyte was used, which is well known for its high ionic conductivity. The Bi anode showed excellent rate-capability up to 16 C-rate, and long cycle life stability with a high reversible capacity of 354 mAh g–1 at 16 C-rate for 50 cycles.


2019 ◽  
Vol 7 (6) ◽  
pp. 2553-2559 ◽  
Author(s):  
Pengxin Li ◽  
Xin Guo ◽  
Shijian Wang ◽  
Rui Zang ◽  
Xuemei Li ◽  
...  

Two-dimensional Sb@TiO2−x nanoplates with abundant voids deliver high reversible capacity, excellent rate capability and stable cycling performance.


2019 ◽  
Vol 55 (77) ◽  
pp. 11575-11578 ◽  
Author(s):  
Jonghyun Choi ◽  
Kyeong-Ho Kim ◽  
Chul-Ho Jung ◽  
Seong-Hyeon Hong

P2-type Na0.7(Ni0.6Co0.2Mn0.2)O2 is synthesized and introduced as a cathode for sodium-ion batteries, which exhibits high reversible capacity, excellent high rate capability and superior long term cyclability.


RSC Advances ◽  
2017 ◽  
Vol 7 (37) ◽  
pp. 23122-23126 ◽  
Author(s):  
Zhenwei Mao ◽  
Min Zhou ◽  
Kangli Wang ◽  
Wei Wang ◽  
Hongwei Tao ◽  
...  

Co3O4@CNFs was fabricated facilely with unique 1D structure of Co3O4 nanoparticles encapsulated in carbon nanofibers, delivering a high reversible capacity of 422.4 mA h g−1 with outstanding rate capability and cycling performance.


2016 ◽  
Vol 4 (17) ◽  
pp. 6472-6478 ◽  
Author(s):  
Bin Cao ◽  
Huan Liu ◽  
Bin Xu ◽  
Yaofei Lei ◽  
Xiaohong Chen ◽  
...  

Mesoporous soft carbon with a high reversible capacity of 331 mA h g−1, excellent rate capability and cycling performance was prepared from mesophase pitch using nano-CaCO3 as the template for sodium-ion batteries.


2017 ◽  
Vol 1 (7) ◽  
pp. 1435-1440 ◽  
Author(s):  
Hongbo Geng ◽  
Jun Yang ◽  
Hong Yu ◽  
Chengchao Li ◽  
Xiaochen Dong

Carbon intercalated porous NaTi2(PO4)3spheres have been synthesized by a facile route. When evaluated as anodes for SIBs, these spheres delivered superior sodium storage performance in terms of high reversible capacity, stable cycling and good rate performances.


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