Infrared spectroscopic observation of the McLafferty rearrangement in ionized 2-pentanone

2020 ◽  
Vol 22 (34) ◽  
pp. 19230-19237
Author(s):  
Ryo Yasumoto ◽  
Yoshiyuki Matsuda ◽  
Asuka Fujii

The isomerization mechanism of ionized 2-pentanone is investigated by infrared predissociation spectroscopy and theoretical calculations. The observation of OH stretch demonstrates its enolization through the McLafferty rearrangement.






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