Infrared spectroscopic observation of the McLafferty rearrangement in ionized 2-pentanone

2020 ◽  
Vol 22 (34) ◽  
pp. 19230-19237
Author(s):  
Ryo Yasumoto ◽  
Yoshiyuki Matsuda ◽  
Asuka Fujii

The isomerization mechanism of ionized 2-pentanone is investigated by infrared predissociation spectroscopy and theoretical calculations. The observation of OH stretch demonstrates its enolization through the McLafferty rearrangement.

2019 ◽  
Vol 877 (2) ◽  
pp. 146 ◽  
Author(s):  
Intae Jung ◽  
Steven L. Finkelstein ◽  
Mark Dickinson ◽  
Taylor A. Hutchison ◽  
Rebecca L. Larson ◽  
...  

2019 ◽  
Vol 58 (35) ◽  
pp. 12010-12013 ◽  
Author(s):  
Allison L. Stelling ◽  
Amy Y. Liu ◽  
Wenjie Zeng ◽  
Raul Salinas ◽  
Maria A. Schumacher ◽  
...  

2009 ◽  
Author(s):  
Takashi Shimonishi ◽  
Takashi Onaka ◽  
Daisuke Kato ◽  
Itsuki Sakon ◽  
Yoshifusa Ita ◽  
...  

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