scholarly journals Steric effects in light-induced solvent proton abstraction

2020 ◽  
Vol 22 (35) ◽  
pp. 19613-19622 ◽  
Author(s):  
Jurick Lahiri ◽  
Mehdi Moemeni ◽  
Ilias Magoulas ◽  
Stephen H. Yuwono ◽  
Jessica Kline ◽  
...  
Keyword(s):  
Excited State ◽  
Steady State ◽  
Transfer Reactions ◽  
Steric Effects ◽  
Structural Factors ◽  
Time Resolved ◽  
Proton Abstraction ◽  
Excited State Proton Transfer ◽  
Proton Transfer Reactions ◽  
Solvent Proton

The significance of solvent structural factors in the excited-state proton transfer reactions of the super photobase FR0-SB with alcohols is examined using steady-state and time-resolved spectroscopy and quantum chemistry computations.

Observation of excited state proton transfer reactions in 2-phenylphenol and 2-phenyl-1-naphthol and formation of quinone methide species

2015 ◽  
Vol 17 (14) ◽  
pp. 9205-9211 ◽  
Author(s):  
Jiani Ma ◽  
Xiting Zhang ◽  
Nikola Basarić ◽  
Peter Wan ◽  
David Lee Phillips
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Transient Absorption ◽  
Intramolecular Proton Transfer ◽  
Quinone Methide ◽  
Transfer Reactions ◽  
Quinone Methides ◽  
Time Resolved ◽  
Excited State Proton Transfer ◽  
Proton Transfer Reactions

Excited state intramolecular proton transfer from a phenol (naphthol) to a carbon atom of the adjacent aromatic ring and formation of quinone methides was studied by femtosecond time-resolved transient absorption.

Exploring the Metric of Excited State Proton Transfer Reactions

2013 ◽  
Vol 117 (50) ◽  
pp. 16165-16173 ◽  
Author(s):  
Marika Savarese ◽  
Paolo A. Netti ◽  
Carlo Adamo ◽  
Nadia Rega ◽  
Ilaria Ciofini
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Transfer Reactions ◽  
Excited State Proton Transfer ◽  
Proton Transfer Reactions

Divergent Hammett Plots of the Ground- and Excited-State Proton Transfer Reactions of 7-Substituted-2-Naphthol Compounds

2019 ◽  
Vol 123 (19) ◽  
pp. 4301-4310 ◽  
Author(s):  
Laura F. Cotter ◽  
Paige J. Brown ◽  
Ryan C. Nelson ◽  
Kana Takematsu
Keyword(s):  
Excited State ◽  
Proton Transfer ◽  
Transfer Reactions ◽  
Excited State Proton Transfer ◽  
Proton Transfer Reactions
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