Bulky bis(aryl)triazenides: just aspiring amidinates? A structural and spectroscopic study

2020 ◽  
Vol 49 (17) ◽  
pp. 5653-5661 ◽  
Author(s):  
Matthew R. Gyton ◽  
Anthony R. Leverett ◽  
Marcus L. Cole ◽  
Alasdair I. McKay

The triazenide ligand is compared to the isoelectronic formamidinate with regards donor capacity, coordination chemistry and capacity to stabilise reactive main group species.

2021 ◽  
Author(s):  
Alex J. Plajer ◽  
Daniel Crusius ◽  
Rajesh B. Jethwa ◽  
Álvaro García-Romero ◽  
Andrew D. Bond ◽  
...  

The coordination chemistry of the air- and moisture-stable main group ligands E(6-Me-2-py)3 (E = As, Sb) and OAs(6-Me-2-py)3 has been investigated with a range of transition metals.


2002 ◽  
Vol 06 (04) ◽  
pp. 259-267 ◽  
Author(s):  
Penelope J. Brothers

Recent advances in the chemistry of main group porphyrin complexes are surveyed. New, unprecedented structural types for porphyrin complexes which have been revealed from the recent reports of boron and tellurium porphyrins are described. Advances in the preparation and reactivity of Group 14 (silicon and tin) and Group 15 porphyrin complexes are discussed. A systematic variation in the out-of-plane distortion (ruffling) of light element Group 14 and 15 porphyrin complexes has become apparent now that a significant number of structurally characterized examples are at hand.


Author(s):  
Matthew E. Carnes ◽  
Nathan R. Lindquist ◽  
Darren W. Johnson

2016 ◽  
Vol 45 (4) ◽  
pp. 1004-1018 ◽  
Author(s):  
Deborah L. Kays

The development of extremely sterically demanding, monodentate amide ligands facilitates the isolation of main group species with new and highly reactive coordination modes. An outstanding feature of these ligands is the ability to tune their steric demands. Reactivity investigations highlight the potential for small molecule activation chemistry and catalysis for these compounds.


1981 ◽  
Vol 222 (1) ◽  
pp. 55-68 ◽  
Author(s):  
G.A. Razuvaev ◽  
A.N. Egorochkin ◽  
S.E. Skobeleva ◽  
V.A. Kuznetsov ◽  
M.A. Lopatin ◽  
...  

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