Transfer hydrogenation of aldehydes and ketones catalyzed using an aminophosphinite POCNH pincer complex of Ni(ii)

2020 ◽  
Vol 49 (34) ◽  
pp. 11950-11957
Author(s):  
Medet Segizbayev ◽  
Özgür Öztopçu ◽  
Davit Hayrapetyan ◽  
Dinmukhamed Shakhman ◽  
Konstantin A. Lyssenko ◽  
...  
Keyword(s):  
Transfer Hydrogenation ◽  
Pincer Complex ◽  
Aldehydes And Ketones ◽  
Metal Ligand

(POCNH)NiBr catalyzes the transfer hydrogenation of aldehydes and ketones in iPrOH. The reactions tolerate alkenes, esters, amides, nitriles, and heterocycles and proceed via the metal–ligand cooperative mechanism through (POCN)NiII species.

scholarly journals Chiral-at-metal iridium complex for efficient enantioselective transfer hydrogenation of ketones

2016 ◽  
Vol 52 (22) ◽  
pp. 4207-4210 ◽  
Author(s):  
Cheng Tian ◽  
Lei Gong ◽  
Eric Meggers
Keyword(s):  
Transfer Hydrogenation ◽  
Iridium Complex ◽  
Asymmetric Transfer Hydrogenation ◽  
Metal Ligand

A pyrazole co-ligand permits a low loading iridium-catalyzed asymmetric transfer hydrogenation which is proposed to proceed through metal–ligand cooperativity.

scholarly journals Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation

2013 ◽  
Vol 32 (15) ◽  
pp. 4114-4121 ◽  
Author(s):  
Bernhard Bichler ◽  
Christian Holzhacker ◽  
Berthold Stöger ◽  
Michael Puchberger ◽  
Luis F. Veiros ◽  
...  
Keyword(s):  
Heterolytic Cleavage ◽  
Pincer Complex ◽  
Metal Ligand

The origin of different driving forces between O–H/N–H functional groups in metal ligand cooperation: mechanistic insight into Mn(i) catalysed transfer hydrogenation

2020 ◽  
Vol 10 (1) ◽  
pp. 169-179 ◽  
Author(s):  
Li Zhou ◽  
Datai Liu ◽  
Haiyi Lan ◽  
Xiujian Wang ◽  
Cunyuan Zhao ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Functional Groups ◽  
Driving Forces ◽  
Transfer Hydrogenation ◽  
Bifunctional Catalysts ◽  
Mechanistic Insight ◽  
Insight Into ◽  
Metal Ligand

The origin of different catalytic activity between two structurally similar Lewis basic bifunctional catalysts.

Reduction of Aldehydes and Ketones by Transfer Hydrogenation with 1,4-Butanediol

2007 ◽  
Vol 9 (21) ◽  
pp. 4387-4389 ◽  
Author(s):  
Hannah C. Maytum ◽  
Bahareh Tavassoli ◽  
Jonathan M. J. Williams
Keyword(s):  
Transfer Hydrogenation ◽  
Aldehydes And Ketones

Potassium Phosphate as a Solid Base Catalyst for the Catalytic Transfer Hydrogenation of Aldehydes and Ketones

ACS Catalysis ◽  
2011 ◽  
Vol 1 (11) ◽  
pp. 1631-1636 ◽  
Author(s):  
Rajitha Radhakrishan ◽  
Dong Minh Do ◽  
Stephan Jaenicke ◽  
Yoel Sasson ◽  
Gaik-Khuan Chuah
Keyword(s):  
Potassium Phosphate ◽  
Transfer Hydrogenation ◽  
Solid Base ◽  
Catalytic Transfer Hydrogenation ◽  
Base Catalyst ◽  
Solid Base Catalyst ◽  
Aldehydes And Ketones ◽  
Catalytic Transfer
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