scholarly journals Stereoselective synthesis of Gly-Gly-type (E)-methylalkene and (Z)-chloroalkene dipeptide isosteres and their application to 14-mer RGG peptidomimetics

RSC Advances ◽  
2020 ◽  
Vol 10 (49) ◽  
pp. 29373-29377
Author(s):  
Hikari Okita ◽  
Yuna Kato ◽  
Tatsuki Masuzawa ◽  
Kosuke Arai ◽  
Sayuri Takeo ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Efficient Synthesis

An efficient synthesis of Gly-Gly-type (E)-methylalkene and (Z)-chloroalkene dipeptide isosteres is realized by organocuprate-mediated single electron transfer reduction.

Reversal of Polarity by Catalytic SET Oxidation: Synthesis of Azabicyclo[m.n.o]alkanes via Chemoselective Reduction of Amidines

2021 ◽  
Author(s):  
Sundarababu Baskaran ◽  
Kirana D V ◽  
Kanak Kanti Das
Keyword(s):  
Electron Transfer ◽  
Stereoselective Synthesis ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Catalytic Method ◽  
One Pot ◽  
Oxidative System ◽  
Oxidation Synthesis

A one-pot catalytic method has been developed for the stereoselective synthesis of cyclopropane-fused cyclic amidines using CuBr2/K2S2O8 as an efficient single electron transfer (SET) oxidative system. The generality of this...

Visible-light-induced phenylchalcogenyl-oxygenation of allenes having aryl or electron withdrawing substituents with ambient air as a sole oxidant

2016 ◽  
Vol 14 (48) ◽  
pp. 11415-11425 ◽  
Author(s):  
Gullapalli Kumaraswamy ◽  
Swargam Vijaykumar ◽  
Kukkadapu Ankamma ◽  
Vykunthapu Narayanarao
Keyword(s):  
Electron Transfer ◽  
Visible Light ◽  
Transfer Process ◽  
Stereoselective Synthesis ◽  
Ambient Air ◽  
Single Electron ◽  
Single Electron Transfer ◽  
Electron Transfer Process ◽  
Electron Withdrawing Substituents

The stereoselective synthesis of α-phenylselenyl- or telluryl β-aryl acrylaldehydes/ketones from aryl allenes/1,3-diarylallene by an oxidative photo-induced single electron transfer process using benign ambient air as a sole oxidant was achieved.

Evidence for single electron transfer in the reaction of alkoxides with alkyl halides

1984 ◽  
Vol 25 (45) ◽  
pp. 5107-5110 ◽  
Author(s):  
E.C. Ashby ◽  
Dong-Hak Bae ◽  
Won-Suh Park ◽  
Robert N. Depriest ◽  
Wei-Yang Su
Keyword(s):  
Electron Transfer ◽  
Alkyl Halides ◽  
Single Electron ◽  
Single Electron Transfer
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