scholarly journals Translational dynamics of a non-degenerate molecular shuttle imbedded in a zirconium metal–organic framework

2021 ◽  
Author(s):  
Benjamin H. Wilson ◽  
Louae M. Abdulla ◽  
Robert W. Schurko ◽  
Stephen J. Loeb

An unsymmetrical molecular shuttle was incorporated into the octahedral cavities of a Zr(iv) MOF. 13C SSNMR showed that the presence of mesitylene in the pores results in an increase in the barriers for the thermally driven motion of the macrocycle.

2019 ◽  
Vol 2019 (22) ◽  
pp. 2674-2679 ◽  
Author(s):  
Sujing Wang ◽  
Mohammad Wahiduzzaman ◽  
Charlotte Martineau-Corcos ◽  
Guillaume Maurin ◽  
Christian Serre

2017 ◽  
Vol 9 (43) ◽  
pp. 37848-37855 ◽  
Author(s):  
Xuerui Wang ◽  
Linzhi Zhai ◽  
Yuxiang Wang ◽  
Ruitong Li ◽  
Xuehong Gu ◽  
...  

Author(s):  
Shi-Chao Qi ◽  
Zhi-Hui Yang ◽  
Rong-Rong Zhu ◽  
Xiao-Jie Lu ◽  
Ding-Ming Xue ◽  
...  

Reproducing the highly efficient catalytic cascade system to mimic life behaviors in vitro has been intensively investigated over the past few decades. However, except the biocatalysis with enzymes, most chemocatalytic...


RSC Advances ◽  
2018 ◽  
Vol 8 (31) ◽  
pp. 17471-17476 ◽  
Author(s):  
Yunhui Yang ◽  
Xiaofei Liu ◽  
Dan Yan ◽  
Ping Deng ◽  
Zhiyong Guo ◽  
...  

A luminescent metal–organic framework have been realized for efficiently sensing hydrazine hydrate.


2018 ◽  
Vol 54 (22) ◽  
pp. 2735-2738 ◽  
Author(s):  
Andrey A. Bezrukov ◽  
Karl W. Törnroos ◽  
Erwan Le Roux ◽  
Pascal D. C. Dietzel

A dimeric Zr12 oxo cluster was used as new molecular building block in construction of metal–organic frameworks utilizing the precursor approach.


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