Exceptional interfacial electrochemistry of few-layered 2D MoS2 quantum sheets for high performance flexible solid-state supercapacitors

2020 ◽  
Vol 8 (26) ◽  
pp. 13121-13131 ◽  
Author(s):  
Swapnil Shital Nardekar ◽  
Karthikeyan Krishnamoorthy ◽  
Parthiban Pazhamalai ◽  
Surjit Sahoo ◽  
Vimal Kumar Mariappan ◽  
...  

Extracting the hidden knowledge behind the exception charge storage mechanism involved in the MoS2 quantum sheets electrode material.

Author(s):  
Cindy Soares ◽  
Begoña Silvan ◽  
Yong-Seok Choi ◽  
Veronica Celorrio ◽  
Giannantonio Cibin ◽  
...  

Here we report the synthesis via ceramic methods of the high-performance Mn-rich Na2.4Al0.4Mn2.6O7 oxygen-redox cathode material for Na-ion batteries which we use as a testbed material to study the effects...


2017 ◽  
Vol 5 (44) ◽  
pp. 22939-22944 ◽  
Author(s):  
Xiaoying Niu ◽  
Guoyin Zhu ◽  
Zhihui Yin ◽  
Ziyang Dai ◽  
Xiaocheng Hou ◽  
...  

Schematic illustration of the fabrication process and charge storage mechanism of the hierarchical Ni wire/Co3O4@MnO2 nanowire array electrode.


2017 ◽  
Vol 5 (30) ◽  
pp. 15661-15668 ◽  
Author(s):  
Justin M. Whiteley ◽  
Simon Hafner ◽  
Sang Sub Han ◽  
Seul Cham Kim ◽  
Viet-Duc Le ◽  
...  

A lithium charge storage mechanism is discovered at the interface of nano-crystallites of LiTiS2in the solid state. The surface titanium atoms can be reduced reversibly at higher voltages. Electrochemically, this appears as a pseudocapacitive effect boosting capacity greater than theoretical at high rate with no liquid electrolyte.


2021 ◽  
Vol 52 ◽  
pp. 277-283 ◽  
Author(s):  
Min Mao ◽  
Xingxing Wu ◽  
Yi Hu ◽  
Qunhui Yuan ◽  
Yan-Bing He ◽  
...  

2021 ◽  
pp. 100928
Author(s):  
Silvio Scaravonati ◽  
Michele Sidoli ◽  
Giacomo Magnani ◽  
Alberto Morenghi ◽  
Marcello Canova ◽  
...  

2017 ◽  
Vol 53 (86) ◽  
pp. 11786-11789 ◽  
Author(s):  
Nutthaphon Phattharasupakun ◽  
Juthaporn Wutthiprom ◽  
Surasak Kaenket ◽  
Thana Maihom ◽  
Jumras Limtrakul ◽  
...  

A proton-conducting coordination polymer of Zn2+ phosphate and protonated imidazole has been used as a novel supercapacitor material in aqueous electrolytes.


2021 ◽  
pp. 915-924
Author(s):  
Yanjiao Ma ◽  
Yuan Ma ◽  
Holger Euchner ◽  
Xu Liu ◽  
Huang Zhang ◽  
...  

2019 ◽  
Author(s):  
Nicolas Goubard-Bretesché ◽  
Olivier Crosnier ◽  
Camille Douard ◽  
Antonella Iadecola ◽  
Richard Retoux ◽  
...  

In nano-sized FeWO<sub>4</sub> electrode material, both Fe and W metal cations are suspected to be involved in the fast and reversible Faradaic surface reactions giving rise to its pseudocapacitive signature. As for any other pseudocapacitive materials, to fully understand the charge storage mechanism, a deeper insight into the involvement of the electroactive cations still has to be provided. The present paper illustrates how operando X-ray absorption spectroscopy (XAS) has been successfully used to collect data of unprecedented quality allowing to elucidate the complex electrochemical behavior of this multicationic pseudocapacitive material. Moreover, these in-depth experiments were obtained in real time upon cycling the electrode, which allowed investigating the reactions occurring in the material within a realistic timescale, which is compatible with electrochemical capacitors practical operation. Both Fe K-edge and W L<sub>3</sub>-edge measurements point out the involvement of the Fe<sup>3+</sup>/Fe<sup>2+</sup> redox couple in the charge storage while W<sup>6+</sup> acts as a spectator cation. The result of this study enables to unambiguously discriminate between the Faradaic and capacitive behavior of FeWO4. Beside these valuable insights toward the full description of the charge storage mechanism in FeWO<sub>4</sub>, this paper demonstrates the potential of operando X-ray absorption spectroscopy to enable a better material engineering for new high capacitance pseudocapacitive electrode materials.


2020 ◽  
Vol 13 (3) ◽  
pp. 949-957 ◽  
Author(s):  
Kevin Robert ◽  
Didier Stiévenard ◽  
Dominique Deresmes ◽  
Camille Douard ◽  
Antonella Iadecola ◽  
...  

Unveiling the charge storage mechanism of vanadium nitride to defy the limits of on-chip micro-supercapacitors.


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