Synthesis of A Chiral Metallo-capsule Composed of Concave Molecules and Chirogenesis upon Fullerene Binding

2021 ◽  
Author(s):  
Masaki Yamamura ◽  
Tsuyoshi Saito ◽  
Toru Hasegawa ◽  
Eiji Nishibori ◽  
Tatsuya Nabeshima
Keyword(s):  
Molecular Capsule

An enantiopure molecular capsule was synthesized quantitatively using complexation of four phosphangulenes as concave molecules with four Zn2+ ions and applied to fullerene binding and chirogenesis. The capsule encapsulated selectively...

Engineering an iridium-containing metal–organic molecular capsule for induced-fit geometrical conversion and dual catalysis

2016 ◽  
Vol 52 (62) ◽  
pp. 9628-9631 ◽  
Author(s):  
Xuezhao Li ◽  
Jinguo Wu ◽  
Liyong Chen ◽  
Xiaoming Zhong ◽  
Cheng He ◽  
...  
Keyword(s):  
Cooperative Binding ◽  
Induced Fit ◽  
Molecular Capsule ◽  
Metal Organic ◽  
Dual Catalysis ◽  
Carbonate Anion

Quantitative dynamic capsule–capsule conversion by cooperative binding one carbonate anion and switchable dual catalysis was achieved within an Ir2Co3-type capsule.

Guest Encapsulation in a Water-Soluble Molecular Capsule Based on Ionic Interactions

2003 ◽  
Vol 125 (33) ◽  
pp. 9946-9947 ◽  
Author(s):  
Francesca Corbellini ◽  
Luigi Di Costanzo ◽  
Mercedes Crego-Calama ◽  
Silvano Geremia ◽  
David N. Reinhoudt
Keyword(s):  
Water Soluble ◽  
Ionic Interactions ◽  
Molecular Capsule

scholarly journals A [13]rotaxane assembled via a palladium molecular capsule

2019 ◽  
Vol 10 (1) ◽  
Author(s):  
Jesus Ferrando-Soria ◽  
Antonio Fernandez ◽  
Deepak Asthana ◽  
Selina Nawaz ◽  
Iñigo J. Vitorica-Yrezabal ◽  
...  
Keyword(s):  
Molecular Capsule

scholarly journals Molecular Capsule Catalysis: Ready to Address Current Challenges in Synthetic Organic Chemistry?

2020 ◽  
Vol 74 (7) ◽  
pp. 561-568
Author(s):  
Ivana Némethová ◽  
Leonidas-Dimitrios Syntrivanis ◽  
Konrad Tiefenbacher
Keyword(s):  
Organic Chemistry ◽  
Building Blocks ◽  
Short Article ◽  
Molecular Capsules ◽  
Synthetic Organic Chemistry ◽  
Size And Shape ◽  
Molecular Capsule ◽  
Hydrophobic Binding ◽  
Binding Pockets ◽  
Self Assembled

Self-assembled molecular capsules, host structures that form spontaneously when their building blocks are mixed, have been known since the 1990s. They share some basic similarities with enzyme pockets, as they feature defined hydrophobic binding pockets that are able to bind molecules of appropriate size and shape. The potential to utilize such host structures for catalysis has been explored since their discovery; however, applications that solve current challenges in synthetic organic chemistry have remained limited. In this short article, we discuss the challenges associated with the use of molecular capsules as catalysts, and highlight some recent applications of supramolecular capsules to overcome challenges in synthetic organic chemistry.

Pairwise selection of guests in a cylindrical molecular capsule of nanometre dimensions

Nature ◽  
10.1038/29501 ◽  
1998 ◽  
Vol 394 (6695) ◽  
pp. 764-766 ◽  
Author(s):  
Thomas Heinz ◽  
Dmitry M. Rudkevich ◽  
Julius Rebek
Keyword(s):  
Molecular Capsule ◽  
Selection Of

A Molecular Capsule Network: Guest Encapsulation and Control of Diels-Alder Reactivity

2010 ◽  
Vol 122 (47) ◽  
pp. 9096-9098 ◽  
Author(s):  
Yasuhide Inokuma ◽  
Shota Yoshioka ◽  
Makoto Fujita
Keyword(s):  
Diels Alder ◽  
Molecular Capsule ◽  
And Control

A fluorescent molecular capsule with a flexible polyaromatic shell for the detection of monoterpene compounds in water

2016 ◽  
Vol 52 (15) ◽  
pp. 3151-3154 ◽  
Author(s):  
Akira Suzuki ◽  
Kei Kondo ◽  
Yoshihisa Sei ◽  
Munetaka Akita ◽  
Michito Yoshizawa
Keyword(s):  
Molecular Capsule

A new molecular capsule composed of U-shaped polyaromatic amphiphiles was synthesized and acts as a fluorescent supramolecular probe for recognizing various monoterpenes in water.

scholarly journals A Molecular Capsule with Revolving Doors Partitioning Its Inner Space

2020 ◽  
Vol 26 (69) ◽  
pp. 16480-16485
Author(s):  
Zhiquan Lei ◽  
Tyler J. Finnegan ◽  
Vageesha W. Liyana Gunawardana ◽  
Radoslav Z. Pavlović ◽  
Han Xie ◽  
...  
Keyword(s):  
Revolving Doors ◽  
Molecular Capsule

scholarly journals Effect of the Lower Molecular Capsule Released from the Cell Surface ofBacillus anthracison the Pathogenesis of Anthrax

2002 ◽  
Vol 186 (2) ◽  
pp. 227-233 ◽  
Author(s):  
Sou‐ichi Makino ◽  
Masahisa Watarai ◽  
Hyeng‐il Cheun ◽  
Toshikazu Shirahata ◽  
Ikuo Uchida
Keyword(s):  
Cell Surface ◽  
Molecular Capsule
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