AIBN-initiated direct thiocyanation of benzylic sp3 C–H with N-thiocyanatosaccharin

2021 ◽  
Vol 57 (77) ◽  
pp. 9938-9941
Author(s):  
Di Wu ◽  
Yongjie Duan ◽  
Kun Liang ◽  
Hongquan Yin ◽  
Fu-Xue Chen
Keyword(s):  
Free Radical ◽  
Reaction Pathway ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
New Strategy

The direct thiocyanation of benzylic compounds was described, and benzyl thiocyanates were synthesized using readily available alkanes as the substrates.

Quantitative PMO Analysis of a Free Radical Reaction Pathway

2010 ◽  
Vol 91 (5) ◽  
pp. 365-365
Author(s):  
Fernando Bernardi ◽  
Andrea Bottoni ◽  
Jaques Fossey
Keyword(s):  
Free Radical ◽  
Reaction Pathway ◽  
Radical Reaction ◽  
Free Radical Reaction

Free-radical conversion of a lignin model compound catalyzed by Pd/C

2015 ◽  
Vol 17 (8) ◽  
pp. 4452-4458 ◽  
Author(s):  
Honglei Fan ◽  
Yingying Yang ◽  
Jinliang Song ◽  
Qinglei Meng ◽  
Tao Jiang ◽  
...  
Keyword(s):  
Free Radical ◽  
Sodium Carbonate ◽  
Model Compound ◽  
Reaction Pathway ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
Lignin Model Compound ◽  
Lignin Model ◽  
Benzyl Phenyl Ether ◽  
Radical Conversion

Benzyl phenyl ether can be decomposed into phenol and toluene effectively by using Pd/C as the catalyst in the presence of sodium carbonate and N-methyl-2-pyrrolidone via a free-radical reaction pathway.

Kinetics of the Production of Castor Oil Maleate through the Autocatalyzed Thermal Reaction and the Free Radical Reaction

2017 ◽  
Vol 50 (2) ◽  
pp. 112-121 ◽  
Author(s):  
Dayanne L. H. Maia ◽  
Elenilson G. Alves Filho ◽  
Antonino F. Barros Junior ◽  
Fabiano A. N. Fernandes
Keyword(s):  
Free Radical ◽  
Castor Oil ◽  
Radical Reaction ◽  
Thermal Reaction ◽  
Free Radical Reaction ◽  
Kinetics Of

Manganese(III)-based oxidative free-radical reaction of α-allyl-β-keto ester with molecular oxygen

1993 ◽  
Vol 34 (52) ◽  
pp. 8509-8512 ◽  
Author(s):  
Takashi Ohshima ◽  
Mikiko Sodeoka ◽  
Masakatsu Shibasaki
Keyword(s):  
Free Radical ◽  
Molecular Oxygen ◽  
Radical Reaction ◽  
Free Radical Reaction ◽  
Keto Ester

scholarly journals Gasification Pathways and Reaction Mechanisms of Primary Alcohols in Supercritical Water

2019 ◽  
Author(s):  
Brian Pinkard ◽  
John Kramlich ◽  
Igor V. Novosselov
Keyword(s):  
Free Radical ◽  
Supercritical Water ◽  
Reaction Mechanisms ◽  
Radical Reaction ◽  
Water Environment ◽  
Waste To Energy ◽  
Reaction Pathways ◽  
Free Radical Reaction ◽  
Reaction Products ◽  
Primary Alcohols

<div> <p></p><p>Supercritical water gasification is a promising waste-to-energy technology with the ability to convert aqueous and/or heterogeneous organic feedstocks to high-value gaseous products. Reaction behavior of complex molecules in supercritical water can be inferred through knowledge of the reaction pathways of model compounds in supercritical water. In this study methanol, ethanol, and isopropyl alcohol are gasified in a continuous supercritical water reactor at temperatures between 500 and 560 °C, and for residence times between 3 and 8 s. <i>In situ</i> Raman spectroscopy is used to rapidly identify and quantify reaction products. The results suggest the dominance of chain-branching, free radical reaction mechanisms that are responsible for decomposing primary alcohols in the supercritical water environment. The presence of a catalytic surface is proposed to be highly significant for initiating radical reactions. Global reaction pathways are proposed, and mechanisms for free radical reaction initiation, propagation, and termination are discussed in light of these and previously published experimental results.</p><br><p></p></div>

scholarly journals Gasification Pathways and Reaction Mechanisms of Primary Alcohols in Supercritical Water

2019 ◽  
Author(s):  
Brian Pinkard ◽  
John Kramlich ◽  
Igor V. Novosselov
Keyword(s):  
Free Radical ◽  
Supercritical Water ◽  
Reaction Mechanisms ◽  
Radical Reaction ◽  
Water Environment ◽  
Waste To Energy ◽  
Reaction Pathways ◽  
Free Radical Reaction ◽  
Reaction Products ◽  
Primary Alcohols

<div> <p></p><p>Supercritical water gasification is a promising waste-to-energy technology with the ability to convert aqueous and/or heterogeneous organic feedstocks to high-value gaseous products. Reaction behavior of complex molecules in supercritical water can be inferred through knowledge of the reaction pathways of model compounds in supercritical water. In this study methanol, ethanol, and isopropyl alcohol are gasified in a continuous supercritical water reactor at temperatures between 500 and 560 °C, and for residence times between 3 and 8 s. <i>In situ</i> Raman spectroscopy is used to rapidly identify and quantify reaction products. The results suggest the dominance of chain-branching, free radical reaction mechanisms that are responsible for decomposing primary alcohols in the supercritical water environment. The presence of a catalytic surface is proposed to be highly significant for initiating radical reactions. Global reaction pathways are proposed, and mechanisms for free radical reaction initiation, propagation, and termination are discussed in light of these and previously published experimental results.</p><br><p></p></div>

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