Silver-Catalyzed Monofluoroalkylation of Heteroarenes with α-Fluorocarboxylic Acids: An Insight of Solvent Effect

2022 ◽  
Author(s):  
Chunfang Guo ◽  
Zhaolong Liu ◽  
Xiangye Li ◽  
Xuliang Han ◽  
Yueyun Li ◽  
...  
Keyword(s):  
Solvent Effect ◽  
Efficient Method

A mild and efficient method for direct C−H monofluoroalkylation of heteroarenes with easily accessible and inexpensive α-fluorocarboxylic acids has been developed. This silver-catalyzed reaction affords mono- and bis-monofluoroalkylated heteroarenes in...

Kinetic Solvent Effects in Organic Reactions

2017 ◽  
Author(s):  
Belinda Slakman ◽  
Richard West
Keyword(s):  
Solvent Effect ◽  
Reaction Kinetics ◽  
Computational Methods ◽  
High Throughput ◽  
Kinetic Modeling ◽  
Solvent Effects ◽  
Reaction Rates ◽  
Prior Work ◽  
Solvent Phase ◽  
High Throughput Manner

<div> <div> <div> <p>This article reviews prior work studying reaction kinetics in solution, with the goal of using this information to improve detailed kinetic modeling in the solvent phase. Both experimental and computational methods for calculating reaction rates in liquids are reviewed. Previous studies, which used such methods to determine solvent effects, are then analyzed based on reaction family. Many of these studies correlate kinetic solvent effect with one or more solvent parameters or properties of reacting species, but it is not always possible, and investigations are usually done on too few reactions and solvents to truly generalize. From these studies, we present suggestions on how best to use data to generalize solvent effects for many different reaction types in a high throughput manner. </p> </div> </div> </div>

An Efficient Method for Estimating Aerodynamic Angles for Small Unmanned Aircraft

2019 ◽  
Author(s):  
Guilherme Barufaldi ◽  
Marcus Victor ◽  
Luiz Carlos Sandoval Góes ◽  
ROBERTO GIL ANNES DA SILVA
Keyword(s):  
Efficient Method ◽  
Unmanned Aircraft ◽  
Aerodynamic Angles
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