Two-Dimensional Stable and Ultrathin Cluster-based Metal-Organic Layers for Efficient Electrocatalytic Water Oxidation

CrystEngComm ◽  
2021 ◽  
Author(s):  
Zheng Yan ◽  
Yan Meng ◽  
Xue Bo Cao ◽  
Bin-Bin Yu ◽  
Jun Wu ◽  
...  

For electrochemical energy conversion, highly efficient and stable electrocatalysts are required, which are principally designed and synthesized by virtue of structural regulations. Two-dimensional Cluster-based Metal-Organic Layers (CMOLs) would have good...

2021 ◽  
pp. 2102801
Author(s):  
Yufei Zhao ◽  
Wen‐Jie Jiang ◽  
Jinqiang Zhang ◽  
Emma C. Lovell ◽  
Rose Amal ◽  
...  

2020 ◽  
Vol 8 (38) ◽  
pp. 19855-19865
Author(s):  
Letícia Mariê Minatogau Ferro ◽  
Anerise de Barros ◽  
Luís Otávio Zaparoli Falsetti ◽  
Cátia Crispilho Corrêa ◽  
Leandro Merces ◽  
...  

Multipurpose analytical platforms that can reliably be adapted to distinct targets are essential nowadays.


2019 ◽  
Vol 12 (1) ◽  
pp. 41-58 ◽  
Author(s):  
Michelle P. Browne ◽  
Zdeněk Sofer ◽  
Martin Pumera

The oxygen evolution and reduction reactions are two extremely important reactions in terms of energy applications.


2021 ◽  
Vol 7 (13) ◽  
pp. eabf3989
Author(s):  
Jiong Wang ◽  
Shuo Dou ◽  
Xin Wang

Heterogeneous molecular catalysts based on transition metal complexes have received increasing attention for their potential application in electrochemical energy conversion. The structural tuning of first and second coordination spheres of complexes provides versatile strategies for optimizing the activities of heterogeneous molecular catalysts and appropriate model systems for investigating the mechanism of structural variations on the activity. In this review, we first discuss the variation of first spheres by tuning ligated atoms; afterward, the structural tuning of second spheres by appending adjacent metal centers, pendant groups, electron withdrawing/donating, and conjugating moieties on the ligands is elaborated. Overall, these structural tuning resulted in different impacts on the geometric and electronic configurations of complexes, and the improved activity is achieved through tuning the stability of chemisorbed reactants and the redox behaviors of immobilized complexes.


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