Luminescence properties and energy transfer of La3Ga5SiO14:Eu3+, Tb3+ phosphors

CrystEngComm ◽  
2021 ◽  
Author(s):  
Xianggang Zuo ◽  
Yi Wang ◽  
Lei Wei ◽  
Xianshun Lv ◽  
Yangbin Fu ◽  
...  

In this paper, a series of Eu3+/Tb3+ doped La3Ga5SiO14 (LGS: Eu3+, Tb3+) phosphors with excellent performance have been synthesized by high-temperature solid-phase method. The effects of Eu3+ and Tb3+ doping...

2011 ◽  
Vol 347-353 ◽  
pp. 3434-3438
Author(s):  
Yan Jun Wei ◽  
Guang Chuan Liang ◽  
Li Wang ◽  
Xiu Qin Ou

Olivine LiFe1−xMnxPO4/C composites were prepared by high temperature solid phase method using MnO2, NH4H2PO4, Li2CO3, FeC2O4•2H2O, glucose as the starting materials. XRD, SEM and constant-current charging/discharging tests were used to study the structure and electrochemical properties of the material. The result showed that when x=0.2 the material exhibited the optimal electrochemical performance, with a higher specific energy of 484.94 Wh/kg.


2012 ◽  
Vol 487 ◽  
pp. 714-718 ◽  
Author(s):  
Sheng Kui Zhong ◽  
Ying Mei Zhang ◽  
Wei Li ◽  
Yue Bin Xu

LiMnPO4cathode material for lithium ion batteries was synthesized by high temperature solid-phase method using MnCO3, Li2CO3, NH4H2PO4as raw materials. The structure of samples was identified by XRD analysis and the particle surface morphology was examined by SEM. The results of XRD showed that the LiMnPO4sample sintered at 700°C for 20h had single ordered olivine structure. The SEM pattern showed that spherical particles distributed uniformly. Respectively, it figured out that the initial charge and discharge capacities of the samples at 0.05C rate were 133.9 and 66.4mAh•g-1.


Materials ◽  
2019 ◽  
Vol 12 (17) ◽  
pp. 2807 ◽  
Author(s):  
Hongyuan Zhao ◽  
Yongfang Nie ◽  
Dongyang Que ◽  
Youzuo Hu ◽  
Yongfeng Li

In this work, the spinel LiMn2O4 cathode material was prepared by high-temperature solid-phase method and further optimized by co-modification strategy based on the Mg-doping and octahedral morphology. The octahedral LiMn1.95Mg0.05O4 sample belongs to the spinel cubic structure with the space group of Fd3m, and no other impurities are presented in the XRD patterns. The octahedral LiMn1.95Mg0.05O4 particles show narrow size distribution with regular morphology. When used as cathode material, the obtained LiMn1.95Mg0.05O4 octahedra shows excellent electrochemical properties. This material can exhibit high capacity retention of 96.8% with 100th discharge capacity of 111.6 mAh g−1 at 1.0 C. Moreover, the rate performance and high-temperature cycling stability of LiMn2O4 are effectively improved by the co-modification strategy based on Mg-doping and octahedral morphology. These results are mostly given to the fact that the addition of magnesium ions can suppress the Jahn–Teller effect and the octahedral morphology contributes to the Mn dissolution, which can improve the structural stability of LiMn2O4.


2019 ◽  
Vol 124 ◽  
pp. 151-156 ◽  
Author(s):  
Lei Yang ◽  
Qianwen Liu ◽  
Hongying Zheng ◽  
Siyuan Zhou ◽  
Wei Zhang

CrystEngComm ◽  
2020 ◽  
Vol 22 (35) ◽  
pp. 5809-5817
Author(s):  
Guangqing Zhang ◽  
Maxim S. Molokeev ◽  
Qianchao Ma ◽  
Xuening Yang ◽  
Shuiquan Han ◽  
...  

Eu3+-Doped Ba3In(PO4)3 was synthesized through a high-temperature solid-phase method.


2012 ◽  
Vol 562-564 ◽  
pp. 482-485
Author(s):  
Zeng Gang Li ◽  
Zeng Yong Chu ◽  
Yong Jiang Zhou ◽  
Hai Feng Cheng

La1-xSrxMnO3 (LSMO) (x=0.1, 0.2, 0.3, 0.4)powders were synthesized by high temperature solid phase method, and the crystal structure and morphology were characterized by XRD and SEM. Results indicated that the pure perovskite type LSMO could be obtained after sintered at the temperature of 1000°C for 6h. The average particle size of the powders decreases with the increasing concentration of Strontium.


RSC Advances ◽  
2019 ◽  
Vol 9 (47) ◽  
pp. 27386-27390
Author(s):  
Yingjun Xiao ◽  
Dongyun Zhang ◽  
Chengkang Chang

A blue emitting phosphor Li2Sr0.9Mg0.1SiO4:Ce3+, with long persistence, was synthesized via a high-temperature solid phase method.


2020 ◽  
Author(s):  
Ning Liu ◽  
Lefu Mei ◽  
Jianxiong Bin ◽  
Zhijian Peng

Abstract The novel scheelite structures of Li2Ca(WO4)2 , Li2Ca2(WO4)(SiO4), and LiCa2(WO4)(PO4) fluorescent materials were successfully prepared using a high-temperature solid-phase method. The compounds were characterized by XRD, EDS, and XRF. The test results showed that the substitution of [WO4]2- by [SiO4]4- /[PO4]3- tetrahedron in tungstate had no significant influence on the crystal structure of the Li2Ca(WO4)2. When Dy3+ ions were introduced as an activator at an optimum doping concentration of 0.08% mol, all of the as-prepared phosphors generated yellow light emissions, and the emission peak was located close to 576 nm. Replacing [WO4]2- with [SiO4]4- /[PO4]3- tetrahedron significantly increased the luminescence of the Li2Ca(WO4)2 phosphors. In addition, the LiCa2(WO4)(PO4):zDy3+ phosphors had the best luminescence properties, decay life (τ = 0.049 ms), and thermal stability (87.8%).


2013 ◽  
Vol 18 ◽  
pp. 547-558 ◽  
Author(s):  
Lingli Wang ◽  
Wanhong Ma ◽  
Yanfen Fang ◽  
Yu Zhang ◽  
Manke Jia ◽  
...  

Author(s):  
V.A. Artyukh ◽  
◽  
V.N. Borsch ◽  
V.S. Yusupov ◽  
S.Ya. Zhuk ◽  
...  

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