Reentrant Structural and Optical Properties of Organic–Inorganic Hybrid Metal Cluster Compound ((n-C4H9)4N)2[Mo6Bri8Bra6]

CrystEngComm ◽  
2022 ◽  
Author(s):  
Norio Saito ◽  
Daiki Nishiyama ◽  
Yoshitaka Matsushita ◽  
Yoshiki Wada ◽  
Stéphane Cordier ◽  
...  

We report the reentrant phase transition of the organic–inorganic hybrid metal cluster (MC) compound (TBA)2[Mo6Bri8Bra6] (TBA = ((n-C4H9)4N)). Structural studies revealed that (TBA)2[Mo6Bri8Bra6] was crystallized in the conventional monoclinic phase...

2011 ◽  
Vol 383-390 ◽  
pp. 3279-3285
Author(s):  
S. Shanmugan ◽  
D. Mutharasu ◽  
Kamarulazizi Ibrahim

25% Zinc doped Cadmium Telluride thin films were prepared using Stacked Elemental Layer method. The structural studies were conducted by the X-Ray technique and the results were compared with standard data which confirmed the presence of mixed phases (CdTe, ZnTe and CdZnTe) in the stack annealed at 425°C. Transmittance spectra depicted the effect of Zn on the optical properties of CdTe thin film. The calculated band gaps from the transmittance spectra were lie between 1.42 and 1.51eV. Scanning Electron Microscope images elucidated the influence of Zn on surface morphology and the grain growth for CdTe thin films.


Nanoscale ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 5215-5221 ◽  
Author(s):  
Guotao Pang ◽  
Xiaoqi Lan ◽  
Ruxue Li ◽  
Zhubing He ◽  
Rui Chen

Temperature-dependent photoluminescence in the phase transition range shows that mixed-organic-cation perovskites are more stable than their pure counterparts.


2017 ◽  
Vol 66 (3) ◽  
pp. 030701
Author(s):  
Guo Hong-Wei ◽  
Liu Ran ◽  
Wang Ling-Rui ◽  
Cui Jin-Xing ◽  
Song Bo ◽  
...  

2016 ◽  
Vol 9 (1) ◽  
pp. 155-163 ◽  
Author(s):  
Claudio Quarti ◽  
Edoardo Mosconi ◽  
James M. Ball ◽  
Valerio D'Innocenzo ◽  
Chen Tao ◽  
...  

We report optical measurements on MAPbI3solar cells, together withab initiosimulations, to investigate the material property changes across the tetragonal to cubic phase transition.


2019 ◽  
Vol 136 (3) ◽  
pp. 498-512
Author(s):  
E.R. Shaaban ◽  
M.Y. Hassaan ◽  
M.G. Moustafa ◽  
Ammar Qasem ◽  
G.A.M. Ali ◽  
...  

2013 ◽  
Vol 774-776 ◽  
pp. 585-588
Author(s):  
Jian Wei Ma ◽  
Ya Rui Song ◽  
Gang Xu

VO2 thin films with thickness from 100 nm down to 2 nm were prepare on C-plane sapphire (0001) substrates by magnetron sputtering and remarkable thickness-dependent structural and optical properties were found. Below 10 nm the films are nonconductive, and their phase transition temperatures are reduced to be much lower than those of the continuous, thick films. Structural defects are believed to be the main reason for this temperature reduction.


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