hoto-sensitive Hybrids Constructed from Diphenyliodonium and Metal-thiocyanates: Photo-induced Structure and Property Transformation

CrystEngComm ◽

10.1039/d1ce01585k ◽

2022 ◽

Author(s):

Kai-Yue Song ◽

Zhencong Yang ◽

Pan-Ke Zhou ◽

Lu-Lu Zong ◽

Hao-Hong Li ◽

...

Keyword(s):

Transition Metal ◽

Structural Transformations ◽

Strong Electron ◽

Structure And Property ◽

Induced Structure

Strong electron-poor cation diphenyliodonium was firstly incorporated with transition metal thiocyanates to obtain three new photo-sensitive hybrids, (DPI)3[Mn(SCN)5(H2O)]∙0.25H2O (α-1), {(DPI)2[Ni(SCN)4]}n (α-2) and {(DPI)6[Cd3(SCN)12]}n (α-3) (DPI+ =diphenyliodonium), whose photo-induced structural transformations...

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Structural Transformations in Two-Dimensional Transition-Metal Dichalcogenide MoS2 under an Electron Beam: Insights from First-Principles Calculations

The Journal of Physical Chemistry Letters ◽

10.1021/acs.jpclett.7b01177 ◽

2017 ◽

Vol 8 (13) ◽

pp. 3061-3067 ◽

Cited By ~ 48

Author(s):

Silvan Kretschmer ◽

Hannu-Pekka Komsa ◽

Peter Bøggild ◽

Arkady V. Krasheninnikov

Keyword(s):

Electron Beam ◽

Transition Metal ◽

First Principles ◽

Structural Transformations ◽

Transition Metal Dichalcogenide ◽

Two Dimensional ◽

First Principles Calculations

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High temperature powder neutron diffraction studies of structural transformations in transition metal hemicarbides M2C1−x

Physica B Condensed Matter ◽

10.1016/0921-4526(89)90581-4 ◽

1989 ◽

Vol 156-157 ◽

pp. 44-46 ◽

Cited By ~ 4

Author(s):

T. Epicier ◽

J. Dubois ◽

C. Esnouf ◽

G. Fantozzi ◽

P. Convert

Keyword(s):

High Temperature ◽

Transition Metal ◽

Neutron Diffraction ◽

Structural Transformations ◽

Powder Neutron Diffraction

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Strong electron-hole symmetric Rashba spin-orbit coupling in graphene/monolayer transition metal dichalcogenide heterostructures

Physical Review B ◽

10.1103/physrevb.96.041409 ◽

2017 ◽

Vol 96 (4) ◽

Cited By ~ 41

Author(s):

Bowen Yang ◽

Mark Lohmann ◽

David Barroso ◽

Ingrid Liao ◽

Zhisheng Lin ◽

...

Keyword(s):

Transition Metal ◽

Orbit Coupling ◽

Graphene Monolayer ◽

Transition Metal Dichalcogenide ◽

Spin Orbit Coupling ◽

Spin Orbit ◽

Electron Hole ◽

Strong Electron ◽

Rashba Spin

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Syntheses of Chelating Tetrazole-Containing Ligands and Studies of Their Palladium(II) and Ruthenium(II) Complexes

Australian Journal of Chemistry ◽

10.1071/ch9951625 ◽

1995 ◽

Vol 48 (9) ◽

pp. 1625 ◽

Cited By ~ 40

Author(s):

AJ Downard ◽

PJ Steel ◽

J Steenwijk

Keyword(s):

Cyclic Voltammetry ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Absorption Spectroscopy ◽

Electronic Absorption ◽

Ph Control ◽

Strong Electron ◽

Ligand Interactions ◽

Metal Ligand

Eleven chelating tetrazole -containing ligands have been synthesized, and their complexes with palladium(II) and ruthenium(II) prepared. Proton n.m.r. spectroscopy, electronic absorption spectroscopy and cyclic voltammetry have been used to study the nature of the metal-ligand interactions in these complexes. The negatively charged tetrazolate group is shown to be a strong electron donor with very different properties to those of the protonated or alkylated tetrazole group. This leads to pH control of the properties of transition metal complexes containing such ligands.

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