In situ quantitative study of the phase transition in surfactant adsorption layers at the silica–water interface using total internal reflection Raman spectroscopy

Author(s):  
Thong Q. Ly ◽  
Fangyuan Yang ◽  
Steven Baldelli

Dimethyldodecylamine N-oxide (DDAO) shows high surface activity with two distinct energy states at the hydrophilic silica/aqueous solution interface studied by total internal reflection (TIR) Raman spectroscopy combined with ratiometric and kinetic analysis.

2013 ◽  
Vol 400 ◽  
pp. 140-146 ◽  
Author(s):  
Aaron M. Jubb ◽  
Dominique Verreault ◽  
Ralf Posner ◽  
Louise J. Criscenti ◽  
Lynn E. Katz ◽  
...  

1999 ◽  
Vol 5 (S2) ◽  
pp. 66-67
Author(s):  
Andre’ J. Sommer ◽  
Mark Hardgrove

Over the past several years many developments have taken place in the field of molecular spectroscopy. For Raman spectroscopy many of the improvements have arisen from technological innovations that include diode-based lasers, holographic notch filters and charged coupled detectors. In contrast, a majority of the developments in infrared spectroscopy have been in the area of new sampling accessories. A major emphasis has been placed on attenuated total internal reflection (ATR) accessories. The devices are allowing infrared spectroscopy to be employed in process control environments and quality control laboratories where the method is not only robust but has the advantages of limited sample preparation and/or in situ analysis.In the realm of microspectroscopy, ATR accessories have the added advantages of providing better spatial resolution, equal to or higher S/N for equivalent sample size compared to transmission measurements and most importantly the ability to collect spectra of small samples without the adverse effect of diffraction. One accessory which was developed several years ago is known as the Split-Pea.


1999 ◽  
Vol 12 (3-6) ◽  
pp. 399-407 ◽  
Author(s):  
J Krägel ◽  
R Wüstneck ◽  
F Husband ◽  
P.J Wilde ◽  
A.V Makievski ◽  
...  

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