Spectroscopic detection of gas-phase HOSO2

2021 ◽  
Author(s):  
Masakazu Nakajima ◽  
Y. Endo
Keyword(s):  
Gas Phase ◽  
Discharge Plasma ◽  
Microwave Spectroscopy ◽  
Gas Mixture ◽  
Torsional Motion ◽  
Tunneling Splittings

The HOSO2 radical was detected by microwave spectroscopy in a discharge plasma of a \SO2/H2O gas mixture. The observed spectrum shows tunneling splittings due to the OH torsional motion. A...

Gas-phase pyrolysis of trans 3-pentenenitrile: competition between direct and isomerization-mediated dissociation

2021 ◽  
Vol 23 (11) ◽  
pp. 6462-6471
Author(s):  
Piyush Mishra ◽  
Sean M. Fritz ◽  
Sven Herbers ◽  
Alexander M. Mebel ◽  
Timothy S. Zwier
Keyword(s):  
Gas Phase ◽  
Molecular Beam ◽  
Microwave Spectroscopy ◽  
Radical Species ◽  
Flash Pyrolysis

The flash pyrolysis of trans 3-pentenenitrile was studied by mass-correlated broadband microwave spectroscopy, where both molecular and radical species were observed within our jet-cooled molecular beam, including 2,4-pentadienenitrile.

scholarly journals An Atmospheric Origin for HCN-Derived Polymers on Titan

Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 965
Author(s):  
Zoé Perrin ◽  
Nathalie Carrasco ◽  
Audrey Chatain ◽  
Lora Jovanovic ◽  
Ludovic Vettier ◽  
...  
Keyword(s):  
Chemical Composition ◽  
Gas Phase ◽  
Formation Process ◽  
Upper Atmosphere ◽  
Gas Mixture ◽  
Space Probe ◽  
Atmospheric Haze ◽  
Formation And Evolution ◽  
Haze Formation

Titan’s haze is strongly suspected to be an HCN-derived polymer, but despite the first in situ measurements by the ESA-Huygens space probe, its chemical composition and formation process remain largely unknown. To investigate this question, we simulated the atmospheric haze formation process, experimentally. We synthesized analogues of Titan’s haze, named Titan tholins, in an irradiated N2–CH4 gas mixture, mimicking Titan’s upper atmosphere chemistry. HCN was monitored in situ in the gas phase simultaneously with the formation and evolution of the haze particles. We show that HCN is produced as long as the particles are absent, and is then progressively consumed when the particles appear and grow. This work highlights HCN as an effective precursor of Titan’s haze and confirms the HCN-derived polymer nature of the haze.

Persulfate activation in gas phase surface discharge plasma for synergetic removal of antibiotic in water

2018 ◽  
Vol 337 ◽  
pp. 446-454 ◽  
Author(s):  
Shoufeng Tang ◽  
Deling Yuan ◽  
Yandi Rao ◽  
Na Li ◽  
Jinbang Qi ◽  
...  
Keyword(s):  
Gas Phase ◽  
Discharge Plasma ◽  
Surface Discharge ◽  
Persulfate Activation ◽  
Phase Surface

Gas-phase structures of ethynyl- and vinyl pentafluorosulfur derivatives: an electron diffraction and microwave spectroscopy study

1991 ◽  
Vol 249 (2-4) ◽  
pp. 285-295 ◽  
Author(s):  
Petra Zylka ◽  
Dines Christen ◽  
Heinz Oberhammer ◽  
Gary L. Gard ◽  
R.J. Terjeson
Keyword(s):  
Electron Diffraction ◽  
Gas Phase ◽  
Microwave Spectroscopy ◽  
Spectroscopy Study ◽  
Phase Structures

Microwave Spectroscopy Measurements of the Gas-Phase Structure of Cyclopentadienyltungsten Tricarbonyl Hydride

2005 ◽  
Vol 24 (12) ◽  
pp. 2848-2853 ◽  
Author(s):  
Chakree Tanjaroon ◽  
Chandana Karunatilaka ◽  
Kristen S. Keck ◽  
Stephen G. Kukolich
Keyword(s):  
Gas Phase ◽  
Phase Structure ◽  
Microwave Spectroscopy ◽  
Gas Phase Structure
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