Coordination polymers of 5-substituted 1,2,3,4-tetracyanocyclopentadienides: structural and electrochemical properties of complex compounds of 5-amino- and 5-nitro-tetracyanocyclopentadienide

2021 ◽  
Author(s):  
Patrick Nimax ◽  
Nils Rotthowe ◽  
Florian Zoller ◽  
Tobias Blockhaus ◽  
Friedrich Ernst Wagner ◽  
...  

Compounds of the 5-amino- (ATCC) and 5-nitro-1,2,3,4-tetracyanocyclopentadienide (NTCC) ligand with iron(II) and iron(III), silver(I) and potassium(I) were prepared and characterized by electrochemical methods using EPR, cyclic voltammetry and Mößbauer spectroscopy...

1987 ◽  
Vol 65 (11) ◽  
pp. 2649-2655 ◽  
Author(s):  
S. P. Mallela ◽  
K. Lee ◽  
P. F. Gehrs ◽  
J. I. Christensen ◽  
J. R. Sams ◽  
...  

The synthesis of a series of hetero-bimetallic fluorosulfate bridged coordination polymers of the type M(II)Sn(SO3F)6, with M(II) = Mn, Fe, Co, Ni, or Cu, by interaction of the metal bisfluorosulfate with the strong fluorosulfate acceptor Sn(SO3F)4 in fluorosulfuric acid is described. Subsequent solvolysis of either stoichiometric 1:1 mixtures of M(SO3F)2 and Sn(SO3F)4or the bimetallic polymer M(II)Sn(IV)(SO3F)6 in an excess of trifluoromethyl sulfuric acid affords the corresponding SO3CF3-bridged polymers of the composition M(II)Sn(SO3CF3)6 with M(II) = Mn, Fe, Co, Ni, or Cu. The new compounds are characterized by infrared and 119Sn Mössbauer spectroscopy.


1979 ◽  
Vol 40 (C2) ◽  
pp. C2-14-C2-16
Author(s):  
T. Toriyama ◽  
K. Saneyoshi ◽  
K. Hisatake

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-534-C6-534
Author(s):  
J. H. HOLLOWAY ◽  
G. J. SCHROBILGEN ◽  
S. BUKSHPAN ◽  
W. HILBRANTS ◽  
H. DE WAARD

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