Bimetallic Complexes that merge Metallocene and Pincer-Metal Building Blocks: Synthesis, Stereochemistry and Catalytic Reactivity

2022 ◽  
Author(s):  
David Morales-Morales ◽  
Hugo Valdes ◽  
Juan Manuel German-Acacio ◽  
G van Koten
Keyword(s):  
Metal Complex ◽  
Building Blocks ◽  
Bimetallic Complexes ◽  
Catalytic Reactivity ◽  
Metal Building

This perspective is to illustrate the synthesis and applications of bimetallic complexes by merging a metallocene and a (cyclopentadienyl/aryl) pincer metal complex. Four possible ways to merge metallocene and pincer-metal...

New Magnetically Coupled Bimetallic Complexes as Potential Building Blocks for Magnetic Materials

1998 ◽  
Vol 4 (11) ◽  
pp. 2173-2181 ◽  
Author(s):  
Scott W. Gordon-Wylie ◽  
Brian L. Claus ◽  
Colin P. Horwitz ◽  
Yan Leychkis ◽  
José M. Workman ◽  
...  
Keyword(s):  
Magnetic Materials ◽  
Building Blocks ◽  
Bimetallic Complexes

scholarly journals Three host peculiarities of a cycloalkane-based micelle toward large metal-complex guests

2020 ◽  
Vol 11 (1) ◽  
Author(s):  
Mamiko Hanafusa ◽  
Yamato Tsuchida ◽  
Kyosuke Matsumoto ◽  
Kei Kondo ◽  
Michito Yoshizawa
Keyword(s):  
Metal Complex ◽  
Building Blocks ◽  
Core Diameter ◽  
Solution State ◽  
Hydrophobic Cavity ◽  
Sterically Demanding ◽  
Linear Alkanes ◽  
Spherical Core ◽  
Quantitative Manner ◽  
Efficient Uptake

AbstractLinear alkanes are essential building blocks for natural and artificial assemblies in water. As compared with typical, linear alkane-based micelles and recent aromatic micelles, we herein develop a cycloalkane-based micelle, consisting of bent amphiphiles with two cyclohexyl frameworks. This uncommon type of micelle, with a spherical core diameter of ~ 2 nm, forms in water in a spontaneous and quantitative manner. The cycloalkane-based, hydrophobic cavity displays peculiar host abilities as follows: (i) highly efficient uptake of sterically demanding Zn(II)-tetraphenylporphyrin and rubrene dyes, (ii) selective uptake of substituted Cu(II)-phthalocyanines and spherical nanocarbons, and (iii) uptake-induced solution-state emission of [Au(I)-dimethylpyrazolate]3 in water. These host functions toward the large metal-complex and other guests studied herein remain unaccomplished by previously reported micelles and supramolecular containers.

Photophysical and Theoretical Studies on Luminescent Tetranuclear Coinage Metal Building Blocks

2006 ◽  
Vol 25 (15) ◽  
pp. 3639-3646 ◽  
Author(s):  
Eduardo J. Fernández ◽  
Antonio Laguna ◽  
José M. López-de-Luzuriaga ◽  
Miguel Monge ◽  
Manuel Montiel ◽  
...  
Keyword(s):  
Building Blocks ◽  
Theoretical Studies ◽  
Coinage Metal ◽  
Metal Building

Truncated octahedral coordination cage incorporating six tetranuclear-metal building blocks and twelve linear edges

2012 ◽  
Vol 3 (7) ◽  
pp. 2321 ◽  
Author(s):  
Kecai Xiong ◽  
Feilong Jiang ◽  
Yanli Gai ◽  
Daqiang Yuan ◽  
Lian Chen ◽  
...  
Keyword(s):  
Building Blocks ◽  
Octahedral Coordination ◽  
Metal Building
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