Highly sensitive analysis of trace elements in aqueous solutions using surface-enhanced and discharge-assisted laser-induced breakdown spectroscopy

2022 ◽  
Author(s):  
Qiuyun Wang ◽  
Ting Ge ◽  
Yitong Liu ◽  
Luyun Jiang ◽  
Anmin Chen ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Trace Elements ◽  
Quantitative Analysis ◽  
Aqueous Solutions ◽  
Laser Induced Breakdown Spectroscopy ◽  
Sensitive Analysis ◽  
Breakdown Spectroscopy ◽  
Highly Sensitive ◽  
Surface Enhanced ◽  
Laser Induced Breakdown

By combining surface-enhanced and discharge-assisted laser-induced breakdown spectroscopy (LIBS), the study successfully realized the quantitative analysis of trace heavy metal Cr, Cu, and Pb in aqueous solutions. We used an...

Highly sensitive analysis of trace Pb in aqueous solution using electro-deposition and spark-discharge assisted laser-induced breakdown spectroscopy

2021 ◽  
Author(s):  
Qiuyun Wang ◽  
Anmin Chen ◽  
Yutong Chen ◽  
Yuanfei Jiang ◽  
Suyu Li ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Heavy Metal ◽  
Spark Discharge ◽  
Laser Induced Breakdown Spectroscopy ◽  
Deposition Method ◽  
Sensitive Analysis ◽  
Electro Deposition ◽  
Breakdown Spectroscopy ◽  
Highly Sensitive ◽  
Laser Induced Breakdown

This study used laser-induced breakdown spectroscopy (LIBS) combined with spark discharge (SD) and electro-deposition method to analyze trace heavy metal Pb in an aqueous solution. First, the electro-deposition method was...

scholarly journals The effectiveness of laser-induced breakdown spectroscopy (LIBS) as a quantitative tool for environmental characterization

2021 ◽  
Author(s):  
Elizabeth Corriveau ◽  
Ashley Mossell ◽  
Holly VerMeulen ◽  
Samuel Beal ◽  
Jay Clausen
Keyword(s):  
Heavy Metal ◽  
Quantitative Analysis ◽  
Homeland Security ◽  
Inductively Coupled Plasma ◽  
Low Cost ◽  
Emission Spectrometry ◽  
Laser Induced Breakdown Spectroscopy ◽  
Cold Temperatures ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

Laser-induced breakdown spectroscopy (LIBS) is a rapid, low-cost analytical method with potential applications for quantitative analysis of soils for heavy metal contaminants found in military ranges. The Department of Defense (DoD), Army, and Department of Homeland Security (DHS) have mission requirements to acquire the ability to detect and identify chemicals of concern in the field. The quantitative potential of a commercial off-the-shelf (COTS) hand-held LIBS device and a classic laboratory bench-top LIBS system was examined by measuring heavy metals (antimony, tungsten, iron, lead, and zinc) in soils from six military ranges. To ensure the accuracy of the quantified results, we also examined the soil samples using other hand-held and bench-top analytical methods, to include Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) and X-Ray Fluorescence (XRF). The effects of soil heterogeneity on quantitative analysis were reviewed with hand-held and bench-top systems and compared multivariate and univariate calibration algorithms for heavy metal quantification. In addition, the influence of cold temperatures on signal intensity and resulting concentration were examined to further assess the viability of this technology in cold environments. Overall, the results indicate that additional work should be performed to enhance the ability of LIBS as a reliable quantitative analytical tool.

Quantitative Determination of Heavy Metal Element Pb in Aqueous Solutions by Laser-Induced Breakdown Spectroscopy Using Paper Slice Substrates

2011 ◽  
Vol 38 (8) ◽  
pp. 0815003 ◽  
Author(s):  
修俊山 Xiu Junshan ◽  
侯华明 Hou Huaming ◽  
钟石磊 Zhong Shilei ◽  
王振南 Wang Zhennan ◽  
卢渊 Lu Yuan ◽  
...  
Keyword(s):  
Heavy Metal ◽  
Aqueous Solutions ◽  
Quantitative Determination ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Metal Element ◽  
Laser Induced Breakdown ◽  
Heavy Metal Element

Standard Reference Line Combined with One-Point Calibration-Free Laser-Induced Breakdown Spectroscopy (CF-LIBS) to Quantitatively Analyze Stainless and Heat Resistant Steel

2018 ◽  
Vol 72 (8) ◽  
pp. 1183-1188 ◽  
Author(s):  
Hongbo Fu ◽  
Huadong Wang ◽  
Junwei Jia ◽  
Zhibo Ni ◽  
Fengzhong Dong
Keyword(s):  
Trace Elements ◽  
Quantitative Analysis ◽  
Reference Line ◽  
Laser Induced Breakdown Spectroscopy ◽  
Resistant Steel ◽  
Heat Resistant Steel ◽  
Breakdown Spectroscopy ◽  
Heat Resistant ◽  
Laser Induced Breakdown ◽  
Calibration Free

Due to the influence of self-absorption of major elements, scarce observable spectral lines of trace elements, and relative efficiency correction of experimental system, accurate quantitative analysis with calibration-free laser-induced breakdown spectroscopy (CF-LIBS) is in fact not easy. In order to overcome these difficulties, standard reference line (SRL) combined with one-point calibration (OPC) is used to analyze six elements in three stainless-steel and five heat-resistant steel samples. The Stark broadening and Saha-Boltzmann plot of Fe are used to calculate the electron density and the plasma temperature, respectively. In the present work, we tested the original SRL method, the SRL with the OPC method, and intercept with the OPC method. The final calculation results show that the latter two methods can effectively improve the overall accuracy of quantitative analysis and the detection limits of trace elements.

On the performance of laser-induced breakdown spectroscopy for quantitative analysis of minor and trace elements in glass

2015 ◽  
Vol 30 (2) ◽  
pp. 417-425 ◽  
Author(s):  
Erwan Negre ◽  
Vincent Motto-Ros ◽  
Frederic Pelascini ◽  
Sandrine Lauper ◽  
Danielle Denis ◽  
...  
Keyword(s):  
Trace Elements ◽  
Quantitative Analysis ◽  
Elemental Analysis ◽  
Laser Induced Breakdown Spectroscopy ◽  
Minor And Trace Elements ◽  
Figures Of Merit ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown ◽  
Laboratory Prototype ◽  
Analytical Figures Of Merit

The analytical figures of merit of laser-induced breakdown spectroscopy (LIBS) for elemental analysis of glass have been evaluated using a laboratory prototype of the LIBS instrument for the quantification of 4 elements, Ti, Cr, Ca and Ba.

Rapid quantitative analysis of trace elements in plutonium alloys using a handheld laser-induced breakdown spectroscopy (LIBS) device coupled with chemometrics and machine learning

2021 ◽  
Author(s):  
Ashwin P. Rao ◽  
Phillip R. Jenkins ◽  
Dung M Vu ◽  
John D. Auxier ◽  
Anil K Patnaik ◽  
...  
Keyword(s):  
Machine Learning ◽  
Trace Elements ◽  
Quantitative Analysis ◽  
Chemometric Analysis ◽  
Laser Induced Breakdown Spectroscopy ◽  
Breakdown Spectroscopy ◽  
Laser Induced Breakdown

We present the first reported quantification of trace elements in plutonium via a portable laser-induced breakdown spectroscopy (LIBS) device and demonstrate the use of chemometric analysis to enhance the handheld...

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