Tuning the optical properties of BODIPY dyes by N-rich heterocycle conjugation using a combined synthesis and computational approach

2021 ◽  
Author(s):  
Jean Michel Merkes ◽  
Tobias Ostlender ◽  
Fufang Wang ◽  
Haitao Sun ◽  
Fabian Kiessling ◽  
...  
Keyword(s):  
Optical Properties ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Computational Approach

The increased number of N-atoms induced a blueshift in absorption and a gain in fluorescence quantum yield, from 750 nm and ~0 % for pyrrole to 635 nm and ~40...

scholarly journals Synthesis of carbon nitride oligomer as a precursor of melon with improved fluorescence quantum yield

2021 ◽  
Vol 2 (18) ◽  
pp. 6083-6093
Author(s):  
Yuto Miyake ◽  
Goichiro Seo ◽  
Kotaro Matsuhashi ◽  
Noriyuki Takada ◽  
Kaname Kanai
Keyword(s):  
Optical Properties ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Carbon Nitride

Melem tetramer, the newly synthesized carbon nitride compound is composed of oligomers with four melem units, is stable in air, and has improved optical properties compared to melon.

Electronic Structure and Optical Response of Electroluminescent Conjugated Polymers

1997 ◽  
Vol 488 ◽  
Author(s):  
J. L. Bredas ◽  
J. Cornil ◽  
D. Beljonne ◽  
D. A. Dos Santos ◽  
Z. Shuaiv ◽  
...  
Keyword(s):  
Experimental Data ◽  
Optical Properties ◽  
Electronic Structure ◽  
Quantum Yield ◽  
Conjugated Polymers ◽  
Quantum Chemical Calculations ◽  
Theoretical Approach ◽  
Quantum Chemical ◽  
Fluorescence Quantum Yield ◽  
Remarkable Agreement

AbstractIn this contribution, we investigate by means of correlated quantum-chemical calculations the influence of intermolecular interactions on the absorption and emission properties of conjugated chains. Various strategies are suggested to avoid a substantial decrease in fluorescence quantum yield in condensed media. Finally, the reliability of our theoretical approach is validated by showing the remarkable agreement obtained between the experimental data and the calculated optical properties of clusters formed by sexithienyl molecules.

The Synthesis and Electro-Optical Properties of Perylene Dicarboximide Dimer with Electron Withdrawing Groups

2014 ◽  
Vol 936 ◽  
pp. 950-954
Author(s):  
Hui Min Wei ◽  
Nan Zhao ◽  
Nan Jiang ◽  
Wen Feng Duan ◽  
Bao Xiang Gao
Keyword(s):  
Optical Properties ◽  
Quantum Yield ◽  
Electron Affinity ◽  
Fluorescence Quantum Yield ◽  
Nmr Spectra ◽  
Band Gaps ◽  
Reduction Wave ◽  
Positive Potential ◽  
H Nmr ◽  
C Nmr

Perylene dicarboximide dimer with electron withdrawing groups were synthesized and fully characterized by 1H-NMR and 13C-NMR spectra. The effects of the substituted groups on the optical and electrochemical properties of the two compounds were investigated. The ∏-∏* absorption peak of the perylene dicarboximide dimer compounds were red shifted from 525nm to 535nm. The band gaps of the dimer could be tuned from 2.28 eV to 2.13 eV. The first reduction wave of the dimer with electron withdrawing groups is shifted by 60 mV to more positive potential compared to that of perylene dicarboximide, suggesting the enhanced electron affinity. Furthemore, the dimer exhibited intermolecular aggregation, and decrease fluorescence quantum yield.

A Study of the Optical Properties of Triazene-Cinnamic Acid Polymeric Fluorescent Brighteners

2012 ◽  
Vol 184-185 ◽  
pp. 868-871
Author(s):  
Jing Liu
Keyword(s):  
Optical Properties ◽  
Quantum Yield ◽  
Aqueous Solutions ◽  
Cinnamic Acid ◽  
Fluorescence Quantum Yield ◽  
Solvent Polarity ◽  
Polymerization Reaction ◽  
Dimethyl Formamide ◽  
Coating Application ◽  
Light Stability

Series of the triazene-cinnamic acid polymeric fluorescent brighteners were synthesized through three-step condensation reactions and polymerization reaction with styrene under replacing one of amino compounds of traditional fluorescent brighteners by cinnamic acid. The optical properties in aqueous solutions and N,N’- dimethyl formamide as well as paper coating application test were evaluated. The results showed that the light stability and fluorescence quantum yield of polymeric fluorescent brighteners was improved obviously and photoinduced isomerization was lower. Meanwhile the optical properties of polymeric fluorescent brightener were affected by concentration and solvent polarity, fluorescence quantum yield increasing and hypochromatic shift of fluorescence emmission wavelength with the decrease of solvent polarity. When the concentration was over 1 10-4 g/mL, the fluorescence was quenched.

UV-Trained and Metal-Enhanced Fluorescence of Biliverdin and Biliverdin Nanoparticles

Nanoscale ◽  
2021 ◽  
Author(s):  
Parinaz Fathi ◽  
Ayman Roslend ◽  
Kritika Mehta ◽  
Parikshit Moitra ◽  
Kai Zhang ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Biomedical Imaging ◽  
Enhanced Fluorescence ◽  
Metal Enhanced Fluorescence

Increasing the fluorescence quantum yield of fluorophores is of great interest for in vitro and in vivo biomedical imaging applications. At the same time, photobleaching and photodegradation resulting from continuous...

Internal Conversion with 3,5-Dimethyl-4-(methylamino)benzonitrile in Alkane Solvents

2000 ◽  
Vol 214 (11) ◽  
Author(s):  
I. Rückert ◽  
A. Hebecker ◽  
A.B.J. Parusel ◽  
K.A. Zachariasse
Keyword(s):  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Internal Conversion ◽  
Alkane Solvents

With 3,5-dimethyl-4-(methylamino)benzonitrile (MHD) in n-hexane and n-hexadecane at 25°C, relatively small values are obtained for the fluorescence quantum yield Φ

Dramatic reduction in fluorescence quantum yield in mutants of Green Fluorescent Protein due to fast internal conversion

1998 ◽  
Vol 237 (1-2) ◽  
pp. 183-193 ◽  
Author(s):  
Andreas D Kummer ◽  
Christian Kompa ◽  
Harald Lossau ◽  
Florian Pöllinger-Dammer ◽  
Maria E Michel-Beyerle ◽  
...  
Keyword(s):  
Green Fluorescent Protein ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Internal Conversion ◽  
Fluorescent Protein ◽  
Dramatic Reduction ◽  
Green Fluorescent

New soluble 4-(4-formyl-2,6-dimethoxyphenoxy) substituted phthalocyanines: Synthesis, characterization, photophysical and photochemical properties

2021 ◽  
pp. 1-10
Author(s):  
Ibrahim Erden ◽  
Betül Karadoğan ◽  
Fatma Aytan Kılıçarslan ◽  
Göknur Yaşa Atmaca ◽  
Ali Erdoğmuş
Keyword(s):  
Quantum Yield ◽  
Singlet Oxygen ◽  
Fluorescence Quantum Yield ◽  
Metal Ion ◽  
Mass Spectra ◽  
Quantum Yields ◽  
Therapeutic Outcomes ◽  
Ft Ir ◽  
Photochemical Properties ◽  
New Compounds

This work describes the synthesis, spectral and fluorescence properties of bis 4-(4-formyl-2,6-dimethoxyphenoxy) substituted zinc (ZnPc) and magnesium (MgPc) phthalocyanines. The new compounds have been characterized by elemental analysis, UV-Vis, FT-IR, 1H-NMR and mass spectra. Afterward, the effects of including metal ion on the photophysicochemical properties of the complexes were studied in biocompatible solvent DMSO to analyze their potential to use as a photosensitizer in photodynamic therapy (PDT). The fluorescence and singlet oxygen quantum yields were calculated as 0.04–0.15 and 0.70–0.52 for ZnPc and MgPc, respectively. According to the results, MgPc has higher fluorescence quantum yield than ZnPc, while ZnPc has higher singlet oxygen quantum yield than MgPc. The results show that the synthesized complexes can have therapeutic outcomes for cancer treatment.

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