Metal-Free Sulfonylative Annulations of Alkyl Diiodides with Sulfur Dioxide: Synthesis of Cyclic Aliphatic Sulfones

2021 ◽  
Author(s):  
Xiuwen Jia ◽  
Chunxi Huang ◽  
Xuemei Zhang ◽  
Zhong Lian
Keyword(s):  
Sulfur Dioxide ◽  
Metal Free ◽  
Gaseous Sulfur

A straightforward protocol for cyclic aliphatic sulfones is effectively established via sulfonylative annulations of alkyl diiodides and gaseous sulfur dioxide. In this transformation, SOgen serves as a safe, bench-stable and...

A metal-free route to alkynyl sulfones under photoinduced conditions with the insertion of sulfur dioxide

2020 ◽  
Vol 22 (6) ◽  
pp. 1906-1910 ◽  
Author(s):  
Xinxing Gong ◽  
Min Yang ◽  
Jin-Biao Liu ◽  
Fu-Sheng He ◽  
Xiaona Fan ◽  
...  
Keyword(s):  
Sulfur Dioxide ◽  
Visible Light ◽  
Visible Light Irradiation ◽  
Room Temperature ◽  
Light Irradiation ◽  
Metal Free

A metal-free route to alkynyl sulfones under photoinduced conditions is accomplished, starting from 4-alkyl Hantzsch esters, sulfur dioxide, and alkynyl bromides under visible light irradiation at room temperature.

Flow injection determination of gaseous sulfur dioxide with gas permeation denuder-based online sampling and preconcentration

2002 ◽  
Vol 374 (6) ◽  
pp. 1141-1146 ◽  
Author(s):  
Zhong-Xian Guo ◽  
Yuan-Zong Li ◽  
Xin-Xiang Zhang ◽  
Wen-Bao Chang ◽  
Yun-Xiang Ci
Keyword(s):  
Sulfur Dioxide ◽  
Flow Injection ◽  
Gas Permeation ◽  
Gaseous Sulfur ◽  
Online Sampling

Transition‐Metal‐Free C2‐H Sulfonylation of Quinoline N ‐Oxides via Insertion of Sulfur Dioxide

2019 ◽  
Vol 8 (11) ◽  
pp. 2105-2108 ◽  
Author(s):  
Heng Cai ◽  
Huiyong Yang ◽  
Jun Xu ◽  
Hanyang Bao ◽  
Lin Huang ◽  
...  
Keyword(s):  
Sulfur Dioxide ◽  
Transition Metal ◽  
Metal Free

Kinetics of the Reaction of Solid Anhydrous Potassium Carbonate with Gaseous Sulfur Dioxide

1994 ◽  
Vol 59 (11) ◽  
pp. 2357-2374 ◽  
Author(s):  
Erich Lippert ◽  
Karel Mocek ◽  
Emerich Erdös
Keyword(s):  
Sulfur Dioxide ◽  
Water Vapour ◽  
Potassium Carbonate ◽  
Anhydrous Potassium Carbonate ◽  
Heterogeneous Reaction ◽  
Fixed Bed ◽  
Partial Pressures ◽  
Flow Apparatus ◽  
Gaseous Sulfur ◽  
Kinetics Of

Results are presented of an experimental kinetic study of the heterogeneous reaction between gaseous sulfur dioxide and solid anhydrous potassium carbonate. The measurements were carried out in an all glass kinetic flow apparatus with nitrogen as the carrier gas and a fixed bed of the solid working in the differential regime at atmospheric pressure and a temperature of 423 K (150 °C). The reaction course was studied in dependence on the partial pressures of sulfur dioxide (pSO2) and water vapour (pH2O) in concentration ranges pSO2 = 13 - 430 Pa and pH2O = 0 - 2 100 Pa. In the reaction, water vapour acts as a gaseous catalyst. Based on the experimental data, the corresponding kinetic equation was found together with the numerical values of the relevant rate and equilibrium adsorption constants.

Kinetics of the Reaction Between Solid Active Sodium Carbonate of the Second Generation and the Gaseous Sulfur Dioxide

1996 ◽  
Vol 61 (8) ◽  
pp. 1141-1157 ◽  
Author(s):  
Květoslava Stejskalová ◽  
Zdeněk Bastl ◽  
Karel Mocek
Keyword(s):  
Sulfur Dioxide ◽  
Kinetic Study ◽  
Sodium Carbonate ◽  
Reaction Rate ◽  
Second Generation ◽  
Surface Composition ◽  
Fixed Bed Reactor ◽  
Active Sodium ◽  
Before And After ◽  
Gaseous Sulfur

The results are presented of a detailed experimental kinetic study of the heterogeneous reaction between gaseous sulfur dioxide and the solid active sodium carbonate of the second generation which has been prepared by a controlled thermal dehydration of higher hydrates of the sodium carbonate. The measurements have been carried out in an all-glass kinetic apparatus with an integral fixed-bed reactor. The reaction course was studied in dependence on genesis and nature of the active sodium carbonate, on temperature and on composition of the gas phase. The reaction rate is significantly affected by presence of the water vapour which acts as a gaseous catalyst. Experimental data have been treated by using the model proposed by Erdos (Collect. Czech. Chem. Commun. 32, 1653 (1967), and the values of the effective reaction rate constants have been computed. The kinetic study of active sodium carbonate of the second generation has been completed by the determination of microstructure (SEM) of solid samples before and after reaction, and by determining the solid surface composition before and after reaction by means of electronic spectra (ESCA).

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