scholarly journals High-performance electrocatalyst based on polyazine derived mesoporous nitrogen-doped carbon for oxygen reduction reaction

RSC Advances ◽  
2021 ◽  
Vol 11 (47) ◽  
pp. 29555-29563
Author(s):  
Songlin Zhao ◽  
Fushan Chen ◽  
Qunfeng Zhang ◽  
Lingtao Meng

Nitrogen-doped porous carbon materials have high potential in metal-free electrocatalysts, which is essential for several renewable energy conversion systems.

2017 ◽  
Vol 41 (15) ◽  
pp. 7392-7399 ◽  
Author(s):  
Cancan Wang ◽  
Winston Duo Wu ◽  
Ying Wang ◽  
Dan Xu ◽  
Feng Yan

Gentiana scabraBunge-derived porous carbon materials as high-performance catalysts for the oxygen reduction reaction in both acidic and alkaline solutions were introduced.


2017 ◽  
Vol 4 (7) ◽  
pp. 1231-1237 ◽  
Author(s):  
Suhong Wang ◽  
Lin Liu ◽  
Shi-Ming Wang ◽  
Zhengbo Han

A series of MOF-templated nitrogen-doped porous carbon materials (NPCs) have been synthesized and assayed as high performance electrocatalysts for oxygen reduction reaction (ORRs) in alkaline media.


2019 ◽  
Vol 55 (61) ◽  
pp. 9023-9026 ◽  
Author(s):  
Rui Wu ◽  
Xiaoju Wan ◽  
Jianghai Deng ◽  
Xun Huang ◽  
Siguo Chen ◽  
...  

A high-performance 3D hierarchical porous metal-free N-doped carbon catalyst for oxygen reduction reaction in acidic medium was synthesized with ZnO as a mesoporous template and NaCl as both a macroporous template and a structure protective agent.


Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 864 ◽  
Author(s):  
Zhenhua Yao ◽  
Ruiyang Fan ◽  
Wangyang Ji ◽  
Tingxuan Yan ◽  
Maocong Hu

In this work, non-traditional metal-free polynitrogen chain N8− deposited on a nitrogen-doped carbon nanotubes (PN-NCNT) catalyst was successfully synthesized by a facile cyclic voltammetry (CV) approach, which was further tested in an oxygen reduction reaction (ORR). The formation of PN on NCNT was confirmed by attenuated total reflectance–Fourier transform infrared spectroscopy (ATR-FTIR) and Raman spectroscopy. Partial positive charge of carbon within NCNT facilitated electron transfer and accordingly induced the formation of more PN species compared to CNT substrate as determined by temperature-programmed decomposition (TPD). Rotating disk electrode (RDE) measurements suggested that a higher current density was achieved over PN-NCNT than that on PN-CNT catalyst, which can be attributed to formation of the larger amount of N8− on NCNT. Kinetic study suggested a four-electron pathway mechanism over PN-NCNT. Moreover, it showed long stability and good methanol tolerance, which indicates its great potential application. This work provides insights on designing and synthesizing non-traditional metal-free catalysts for ORR in fuel cells.


2016 ◽  
Vol 4 (7) ◽  
pp. 2581-2589 ◽  
Author(s):  
G. A. Ferrero ◽  
K. Preuss ◽  
A. B. Fuertes ◽  
M. Sevilla ◽  
M.-M. Titirici

High-performance nitrogen-doped carbon electrocatalysts for the oxygen reduction reaction have been synthesized by the rational design of their pore structure.


2020 ◽  
Vol 146 ◽  
pp. 106131
Author(s):  
Xiaobo Chen ◽  
Zhiqiang Li ◽  
Rumeng Qin ◽  
Shengjie Shan ◽  
Yibin Liu ◽  
...  

2019 ◽  
Vol 55 (92) ◽  
pp. 13832-13835 ◽  
Author(s):  
Dongshuang Wu ◽  
Minna Cao ◽  
Hanhui You ◽  
Chuan Zhao ◽  
Rong Cao

The first example of the preparation of nitrogen-doped holey carbon (NHC) with abundant in-plane holes derived from a rigid macrocycle cucurbit[6]uril self-assembly is reported.


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