Efficient N2 Reduction with VS2 Electrocatalyst: Identifying the Active Sites and Unraveling the Reaction Pathway

2021 ◽  
Author(s):  
Liang Zhao ◽  
Rui Zhao ◽  
Yixiang Zhou ◽  
Xiaoxuan Wang ◽  
Xinyue Chi ◽  
...  
Keyword(s):  
Active Sites ◽  
Reaction Pathway ◽  
Reduction Reaction ◽  
Sustainable Production ◽  
Nitrogen Reduction

Electrochemical nitrogen reduction reaction (NRR) is an effective method for sustainable production of NH3. However, a robust NRR electrocatalyst is predominantly required in order to active the inert N2 molecule....

On the mechanism of electrochemical ammonia synthesis on the Ru catalyst

2016 ◽  
Vol 18 (13) ◽  
pp. 9161-9166 ◽  
Author(s):  
Seoin Back ◽  
Yousung Jung
Keyword(s):  
Active Sites ◽  
Hydrogen Adsorption ◽  
Ammonia Synthesis ◽  
Reduction Reaction ◽  
Nitrogen Reduction ◽  
Associative Mechanism ◽  
Ru Catalyst

The nitrogen reduction reaction (NRR) pathways involving various N–N dissociation steps are found to be comparable to the conventional associative mechanism. The competitive hydrogen adsorption and evolution is revealed to negatively affect the NRR for two reasons, an increase in NRR overpotentials as a function of partial H-coverages as well as a decreased number of active sites.

scholarly journals Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride

2019 ◽  
Vol 131 (39) ◽  
pp. 13906-13910 ◽  
Author(s):  
Xuan Yang ◽  
Shyam Kattel ◽  
Jared Nash ◽  
Xiaoxia Chang ◽  
Ji Hoon Lee ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Active Sites ◽  
Reduction Reaction ◽  
Vanadium Nitride ◽  
Nitrogen Reduction

scholarly journals Quantification of Active Sites and Elucidation of the Reaction Mechanism of the Electrochemical Nitrogen Reduction Reaction on Vanadium Nitride

2019 ◽  
Vol 58 (39) ◽  
pp. 13768-13772 ◽  
Author(s):  
Xuan Yang ◽  
Shyam Kattel ◽  
Jared Nash ◽  
Xiaoxia Chang ◽  
Ji Hoon Lee ◽  
...  
Keyword(s):  
Reaction Mechanism ◽  
Active Sites ◽  
Reduction Reaction ◽  
Vanadium Nitride ◽  
Nitrogen Reduction

Synergistic Effect of Active Sites of Double‐Atom Catalysts for Nitrogen Reduction Reaction

ChemSusChem ◽  
2021 ◽  
Author(s):  
Chang Ning Sun ◽  
Zhi Li Wang ◽  
Xing‐You Lang ◽  
Zi Wen ◽  
Qing Jiang
Keyword(s):  
Synergistic Effect ◽  
Active Sites ◽  
Reduction Reaction ◽  
Nitrogen Reduction

Identification of functionality of heteroatoms in boron, nitrogen and fluorine ternary-doped carbon as a robust electrocatalyst for nitrogen reduction reaction powered by rechargeable zinc–air batteries

2020 ◽  
Vol 8 (17) ◽  
pp. 8430-8439 ◽  
Author(s):  
Quan Zhang ◽  
Fang Luo ◽  
Ying Ling ◽  
Shenglin Xiao ◽  
Min Li ◽  
...  
Keyword(s):  
Active Sites ◽  
Reduction Reaction ◽  
Hydrogen Ions ◽  
Nitrogen Reduction ◽  
Adsorption Of Hydrogen ◽  
Boron Nitrogen ◽  
Zinc Air Batteries

Efficient nitrogen reduction reaction (NRR) catalysis relies on the active sites of the electrocatalyst being capable of adsorption of hydrogen ions and nitrogen molecules.

Using the NN dipole as a theoretical indicator for estimating the electrocatalytic performance of active sites in the nitrogen reduction reaction: single transition metal atoms embedded in two dimensional phthalocyanine

2020 ◽  
Vol 8 (7) ◽  
pp. 3598-3605 ◽  
Author(s):  
Fangfang Liu ◽  
Luying Song ◽  
Yunxia Liu ◽  
Fangfang Zheng ◽  
Lu Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Triple Bond ◽  
Active Sites ◽  
Reduction Reaction ◽  
Two Dimensional ◽  
Nitrogen Reduction ◽  
Metal Atoms ◽  
Electrocatalytic Performance ◽  
Transition Metal Atoms ◽  
Single Transition

The dipole of the NN triple bond in an adsorbed N2 molecule as an efficient theoretical indicator for estimating NRR activities.

Unveiling the Genesis of the High Catalytic Activity in Nickel Phthalocyanine for Electrochemical Ammonia Synthesis

2021 ◽  
Author(s):  
Shyamal Murmu ◽  
Sourav Paul ◽  
Samadhan Kapse ◽  
Ranjit Thapa ◽  
Santanu Chattopadhyay ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Active Sites ◽  
Ammonia Synthesis ◽  
Reduction Reaction ◽  
High Catalytic Activity ◽  
Nitrogen Reduction ◽  
Nickel Phthalocyanine ◽  
Bosch Process

Electrochemical ammonia synthesis by nitrogen reduction reaction (NRR) using economically efficient electrocatalyst can provide a substitute of Haber-Bosch process. However, identification of active sites responsible for the origination of catalytic...

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