H2 and CH4 Productions from Bio-alcohols by Condensed Poly (Heptazine Imide) with Visible Light

Author(s):  
Dandan Zheng ◽  
Jingmin Zhou ◽  
Zhongpu Fang ◽  
Tobias Heil ◽  
Aleksandr Savateev ◽  
...  

Photocatalytic H2 production via water splitting holds great potential for the conversion of solar energy into renewable and storable chemical fuels in a sustainable manner, but this up-hill reaction is...

Author(s):  
Zunkun Tan ◽  
Peng Zhang ◽  
Qiaoshan Chen ◽  
Shengqiong Fang ◽  
Guocheng Huang ◽  
...  

Photocatalytic H2 production via water splitting has emerged as an eco-friendly and green technology to efficiently utilize the solar energy. Developing visible light active photocatalysts, especially the metal-free ones is...


Nanoscale ◽  
2015 ◽  
Vol 7 (25) ◽  
pp. 11082-11092 ◽  
Author(s):  
Ruosong Wang ◽  
Xiaoxue Xu ◽  
Yi Zhang ◽  
Zhimin Chang ◽  
Zaicheng Sun ◽  
...  

We have designed a novel semiconductor nanorod film, sensitized with a polymetallic sulfide, for solar energy conversion. Our results verify that it could be conveniently used in micro-nano photoelectronic devices.


Solar Energy ◽  
2003 ◽  
Author(s):  
Hironori Arakawa ◽  
Zhigang Zou ◽  
Kazuhiro Sayama ◽  
Ryu Abe

The photocatalytic splitting of water into hydrogen and oxygen using solar energy is one of the most attractive renewable sources of hydrogen fuel. Therefore, considerable efforts have been paid in developing photocatalysts capable of using visible light, which accounts for about 43% of the solar energy. However such a photocatalyst has not been developed so far. We have developed a new Ni-doped indium-tantalum oxide photocatalyst, In1-xNixTaO4 (x = 0.0∼0.2), which induced direct splitting of water into stoichiometric amount of oxygen and hydrogen under visible light irradiation with a quantum yield of about 0.66% at 420.7 nm. We have also developed a new two-step water splitting system using two different semiconductor photocatalysts, Pt/WO3 photocatalyst for oxygen evolution and Pt/SrTiO3(Cr-Ta-doped) photocatalyst for hydrogen evolution, and a redox mediator, I−/IO3−, mimicking the Z-scheme mechanism of the natural photosynthesis. The quantum yield of this system was about 0.1% at 420.7nm. Both photocatalytic methods are the first examples for visible light water splitting system in the world.


2017 ◽  
Vol 42 (51) ◽  
pp. 30257-30266 ◽  
Author(s):  
J.A. Jiménez-Miramontes ◽  
J.L. Domínguez-Arvizu ◽  
J.M. Salinas-Gutiérrez ◽  
M.J. Meléndez-Zaragoza ◽  
A. López-Ortiz ◽  
...  

Solar Energy ◽  
2004 ◽  
Author(s):  
Ryu Abe ◽  
Kazuhiro Sayama ◽  
Hironori Arakawa

H2 production from a water-acetonitrile mixed solution containing iodide electron donor was investigated over dye-sensitized Pt/TiO2 photocatalysts under visible light irradiation, as a part of water splitting system using iodide redox mediator. The rates of H2 evolution were decreased with the increase of the water ratio in the mixed solutions, because of the decrease in energy gap between the redox potential of I3−/I− and the HOMO levels of the dyes, which lowing the efficiency of electron transfer from I− to dye.


2016 ◽  
Vol 18 (21) ◽  
pp. 14222-14227 ◽  
Author(s):  
Huimei Liu ◽  
Bo Xu ◽  
J.-M. Liu ◽  
Jiang Yin ◽  
Feng Miao ◽  
...  

ReS2is a stable and efficient photocatalyst with potential applications in the use of solar energy for water splitting.


RSC Advances ◽  
2015 ◽  
Vol 5 (24) ◽  
pp. 18642-18646 ◽  
Author(s):  
Naimeh Naseri ◽  
Sajjad Janfaza ◽  
Rowshanak Irani

Bacteriorhodopsin, a visible light sensitizer for the water splitting reaction, adsorbed on TiO 2 nanoparticulate photoanode without any linker and caused a significant PEC enhancement.


2019 ◽  
Vol 48 (5) ◽  
pp. 1662-1671 ◽  
Author(s):  
Paweł Mazierski ◽  
Jakub Sowik ◽  
Magdalena Miodyńska ◽  
Grzegorz Trykowski ◽  
Alicja Mikołajczyk ◽  
...  

Novel visible light responsive materials for water splitting are essential for the efficient conversion of solar energy into hydrogen bond energy.


Catalysts ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 655 ◽  
Author(s):  
Yifan Zhang ◽  
Young-Jung Heo ◽  
Ji-Won Lee ◽  
Jong-Hoon Lee ◽  
Johny BajGai ◽  
...  

Photocatalytic H2 generation via water splitting is increasingly gaining attention as a viable alternative for improving the performance of H2 production for solar energy conversion. Many methods were developed to enhance photocatalyst efficiency, primarily by modifying its morphology, crystallization, and electrical properties. Here, we summarize recent achievements in the synthesis and application of various photocatalysts. The rational design of novel photocatalysts was achieved using various strategies, and the applications of novel materials for H2 production are displayed herein. Meanwhile, the challenges and prospects for the future development of H2-producing photocatalysts are also summarized.


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