Ultralow Thermal Conductivity through the interplay of composition and disorder between thick and thin layers of Makovickyite structure

2021 ◽  
Author(s):  
srikanth Balijapelly ◽  
Ashlee Hauble ◽  
Mathew Pollard ◽  
Morgane Poupon ◽  
Vaclav Petricek ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Homologous Series ◽  
Thin Layers ◽  
Synthesis And Characterization ◽  
Quaternary Complex

Here we report the synthesis and characterization of three quaternary complex chalcogenides, Ag0.72Bi5.48Cu0.88S9 (I), Ag0.70Bi5.30Cu1.3S9 (II), Ag0.34Bi4.54Cu1.98PbS9 (III). All the compounds in this homologous series crystallize in the C2/m space...

Synthesis and characterization of kesterite Cu2ZnSnTe4via ball-milling of elemental powder precursors

RSC Advances ◽  
2016 ◽  
Vol 6 (73) ◽  
pp. 68754-68759 ◽  
Author(s):  
Devendra Pareek ◽  
K. R. Balasubramaniam ◽  
Pratibha Sharma
Keyword(s):  
Solar Cells ◽  
Ball Milling ◽  
Homologous Series ◽  
Elemental Powder ◽  
Synthesis And Characterization ◽  
Chemical Route ◽  
Light Absorber ◽  
Absorber Material

Cu2ZnSnTe4 was synthesized using mechano-chemical route from its elemental precursors. A homologous series of kesterite light absorber material Cu2ZnSnX4 (X: S, Se, Te) can be used for realization of multi-junction solar cells.

Synthesis and Physical Properties of Skutterudite Superlattices

2000 ◽  
Vol 626 ◽  
Author(s):  
Joshua R. Williams ◽  
David C. Johnson ◽  
Michael Kaeser ◽  
Terry Tritt ◽  
George Nolas ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Physical Properties ◽  
High Temperatures ◽  
Synthesis And Characterization ◽  
Superlattice Structure

ABSTRACTPredicted and observed reductions in thermal conductivity of materials with superlattice structure have prompted interesting research into the possibility of using these materials as higher efficiency thermoelectrics. Synthesis of superlattice materials is challenging however, as the structure itself is generally not very stable at high temperatures as it is prone to interdiffusion. Presented here is the successful synthesis and characterization of a superlattice composed of two materials with the skutterudite structure, IrSb3 and CoSb3.

Synthesis and characterization of an homologous series of bis(amido)diazadipnictetidines (Pnict = P, As, Sb, Bi)

2001 ◽  
Vol 79 (3) ◽  
pp. 342-348 ◽  
Author(s):  
Neil Burford ◽  
T Stanley Cameron ◽  
Kim-Chung Lam ◽  
Daren J LeBlanc ◽  
Charles LB Macdonald ◽  
...  
Keyword(s):  
Key Words ◽  
General Formula ◽  
Homologous Series ◽  
Spectroscopic Characterization ◽  
Structural Features ◽  
Synthesis And Characterization ◽  
General Reaction ◽  
Coordinative Unsaturation

Spectroscopic and structural features are presented for the first homologous series of diazadipnictetidines, which have the general formula [DipNPnN(H)Dip]2 (Pn = P, As, Sb, Bi; Dip = 2,6-diisopropylphenyl). The compounds are obtained from a general reaction of the corresponding halopnictine with excess LiN(H)Dip, which was previously reported for [DipNBiN(H)Dip]2. However, isolation is improved by the introduction of LiN(H)-t-Bu (at the appropriate stoichiometry) following the addition of LiN(H)Dip. The intermediate steric presence of the Dip substituent is suitable to support the heterocatenate framework for all homologues. This is in contrast to the small substituents (e.g. alkyl), which enable both bis- and tris-amination, and the larger substituent (Mes* = tri-tert-butylphenyl), which can impose coordinative unsaturation (aminoiminopnictine) for the smaller congeners (P and As).Key words: phosphorus, arsenic, antimony, bismuth, phosphazanes, phosphetidines, synthesis, structures, spectroscopic characterization.

Synthesis and Characterization of a Novel Azoester Homologous Series

2015 ◽  
Vol 606 (1) ◽  
pp. 47-55
Author(s):  
V. C. Kotadiya ◽  
M. D. Khunt ◽  
U. C. Bhoya
Keyword(s):  
Homologous Series ◽  
Synthesis And Characterization

Synthesis and characterization of thermal conductivity of nanofluids based on Ag decorated-CNTs/graphene hybrid materials

2017 ◽  
Vol 59 (4) ◽  
pp. 75-79
Author(s):  
Ngoc Anh Nguyen ◽  
Van Trinh Pham ◽  
Hung Thang Bui ◽  
Van Chuc Nguyen ◽  
Tuan Hong Nguyen ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Hybrid Materials ◽  
Synthesis And Characterization
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