Resonance and non-resonance intermolecular energy exchange in molecular collisions

Abstract. Contributions of intermolecular electron energy transfers in the electronic quenching are calculated for molecular collisions N2(A3Σu+, W3Δu)+N2(X1Σg+, v=0), N2(A3Σu+)+N2(X1Σg+, v≥0), N2(A3Σu+)+O2(X3Σg−, v=0–2), O2(a1Δg, b1Σg+)+O2(X3Σg−, v=0–2). The calculation has allowed one to estimate the product branching ratios. It is shown that there is a dependence of the calculated rate coefficients on the vibrational excitation of N2(X1Σg+) and O2(X3Σg−) molecules. In many cases, the calculated rate coefficients have a good agreement with available experimental data.

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Intermolecular energy exchange as a mechanism for vibrational dephasing in polyatomic molecules

Chemical Physics Letters ◽

10.1016/0009-2614(78)80341-8 ◽

1978 ◽

Vol 57 (1) ◽

pp. 8-14 ◽

Cited By ~ 38

Author(s):

C.B. Harris ◽

R.M. Shelby ◽

P.A. Cornelius

Keyword(s):

Energy Exchange ◽

Polyatomic Molecules ◽

Vibrational Dephasing ◽

Intermolecular Energy

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Resonance and non-resonance intermolecular energy exchange in molecular collisions

Energy Exchange in Molecular Collisions

Intermolecular Energy Exchange by Infrared Radiometry.

ChemInform Abstract: INTERMOLECULAR ENERGY EXCHANGE OF INFRARED-LASER EXCITED CHLORODIFLUOROMETHANE OR SILICON TETRAFLUORIDE WITH BROMINE AT EXCITATION ENERGIES OF 70-200 KJ/MOL

Efficient Intermolecular Energy Exchange and Soft Ionization of Water at Nanoplatelet Interfaces

Allowing for intermolecular energy exchange in the description of relaxation processes in terms of adiabatic variables

Quasi-resonance energy transfer in molecular collisions. Vibrational energy exchange between N2 and CO2 molecules

A comparison of the two‐state approximation and multistate treatments for vibration–vibration energy exchange in molecular collisions

Internal energy exchange in molecular collisions with a crystal

The study of intermolecular energy transfers in electronic energy quenching for molecular collisions N<sub>2</sub>-N<sub>2</sub>, N<sub>2</sub>-O<sub>2</sub>, O<sub>2</sub>-O<sub>2</sub>

Intermolecular energy exchange as a mechanism for vibrational dephasing in polyatomic molecules

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