Ion–solvent interactions of some ions in dipolar aprotic solvents at 25 °C

1990 ◽  
Vol 86 (3) ◽  
pp. 489-494
Author(s):  
Natalija Schmelzer ◽  
Jürgen Einfeldt ◽  
Manfred Grigo
Keyword(s):  
Aprotic Solvents ◽  
Solvent Interactions ◽  
Dipolar Aprotic Solvents

Solvation of ions. XXV. Partial molal volumes of single ions in protic and dipolar aprotic solvents

1975 ◽  
Vol 28 (5) ◽  
pp. 955 ◽  
Author(s):  
MRJ Dack ◽  
KJ Bird ◽  
AJ Parker
Keyword(s):  
Propylene Carbonate ◽  
Dimethyl Sulphoxide ◽  
Aprotic Solvents ◽  
Solvent Interactions ◽  
Partial Molal Volumes ◽  
Steric Crowding ◽  
Solvation Of Ions ◽  
Molal Volumes ◽  
Solvent Molecules ◽  
Dipolar Aprotic Solvents

Partial molal volumes at 25� are reported for some 1 : 1 electrolytes, and for triphenylmethane, in dimethyl sulphoxide, N,N- dimethylformamide, acetonitrile, propylene carbonate, formamide and hexamethylphosphoramide. The assumption that ΔV�tr(Ph4As+) = ΔV�tr(BPh4-) was used to obtain ionic partial molal volumes of transfer from water to the non-aqueous solvents. Solvent compressibility appears to determine the partial molal volumes of non-electrolytes and large hydrophobic ions in solution. Values of ΔV�tr for cations and anions are discussed in terms of ion-solvent interactions, solvent-solvent interactions and steric crowding of large solvent molecules around the ions.

Liquid junction potentials across the interface between the aqueous saturated calomel electrode and some nonaqueous solvents, based on the tatb assumption

1983 ◽  
Vol 36 (9) ◽  
pp. 1779 ◽  
Author(s):  
J Datta ◽  
S Bhattacharya ◽  
KK Kundu
Keyword(s):  
Saturated Calomel Electrode ◽  
Nonaqueous Solvents ◽  
Aprotic Solvents ◽  
Nonaqueous Solvent ◽  
Liquid Junction ◽  
Solvent Interactions ◽  
Electrode Potentials ◽  
Protic Solvents ◽  
Liquid Junction Potentials ◽  
Dipolar Aprotic Solvents

The liquid junction potentials (Ej) across aqueous saturated KCl/nonaqueous solvent junctions have been determined within the framework of the tetraphenylarsonium tetraphenylborate (tatb) extra- thermodynamic assumption. The nonaqueous solvents comprise methanol, ethylene glycol, acetonitrile, propylene carbonate, dimethylformamide and dimethyl sulfoxide. The Ej values obtained are fairly small (below 40 mV) in the case of protic solvents and fairly large (within 100-200 mV) in the case of dipolar aprotic solvents, as expected if primarily guided by solvent-solvent interactions across the liquid junctions. The results allow the aqueous saturated calomel electrode to be used to relate electrode potentials in different solvents.

Solvation of ions by dipolar aprotic solvents and water. A CNDO/2 study

1985 ◽  
Vol 50 (11) ◽  
pp. 2493-2508 ◽  
Author(s):  
Petr Kyselka ◽  
Zdeněk Havlas ◽  
Ivo Sláma
Keyword(s):  
Binary Mixtures ◽  
Quantum Chemical ◽  
Chemical Method ◽  
Molecular Structures ◽  
Dimethyl Sulphoxide ◽  
Ternary Mixtures ◽  
Aprotic Solvents ◽  
Quantum Chemical Method ◽  
Solvation Of Ions ◽  
Dipolar Aprotic Solvents

Solvation of Li+, Be2+, Na+, Mg2+, and Al3+ ions has been studied in binary mixtures with dimethyl sulphoxide, dimethylformamide, acetonitrile and water, and in ternary mixtures of the organic solvents with water. The CNDO/2 quantum chemical method was used to calculate the energies of solvation, molecular structures and charge distributions for the complexes acetonitrile...ion (1:1, 2:1, 4:1), dimethyl sulphoxide...ion (1:1), dimethylformamide...ion (1:1), and acetonitrile (dimethyl sulphoxide, dimethylformamide)...ion...water (1:1:1).

1H and 13C NMR spectra of 2,2’-disubstitutedtrans-azobenzenes suitable for preparation of metallized azo dyes

1991 ◽  
Vol 56 (10) ◽  
pp. 2160-2168 ◽  
Author(s):  
Josef Jirman
Keyword(s):  
Nmr Spectra ◽  
Electron Pair ◽  
Phenyl Group ◽  
Aprotic Solvents ◽  
1H And 13C Nmr ◽  
Predominant Form ◽  
Rapid Equilibrium ◽  
Dipolar Aprotic Solvents ◽  
Free Electron Pair ◽  
C Nmr

The 1H and 13C NMR spectra have been measured of six trans-azobenzenes substituted at 2 and 2’ positions with substituents favourable for complex formation with a metal (OH, NH2, NHCOCH3, COOH). From the standpoint of NMR such substituted trans-azobenzenes are present in solution in a rapid equilibrium following from rotation around the bond between C-1 of phenyl group and N atom of azo linkage. The predominant form has the substituent in the syn-position with respect to the free electron pair of the nearer azo nitrogen atom. The equilibrium is affected by dipolar aprotic solvents (such as hexadeuteriodimethyl sulfoxide) by decreasing the presence of the predominant form by 1 to 11%.

Electron-transfer reactions in non-aqueous media. VII. Reduction of CoF(NH3)52+ and Co(HCOO)(NH3)52+ by copper(I) in dimethyl sulfoxide-water mixtures

1983 ◽  
Vol 36 (10) ◽  
pp. 1923 ◽  
Author(s):  
JMB Harrowfield ◽  
L Spiccia ◽  
DW Watts
Keyword(s):  
Electron Transfer ◽  
Dimethyl Sulfoxide ◽  
Aqueous Media ◽  
Mixed Solvents ◽  
Transfer Reactions ◽  
Aprotic Solvents ◽  
Aqueous Mixtures ◽  
Electron Transfer Reactions ◽  
Dipolar Aprotic Solvents ◽  
Sphere Mechanism

Previous work on the reduction of a series of cobalt(III) complexes by iron(II) in dipolar aprotic solvents and in aqueous mixtures has been extended to reduction by copper(I). The greater stability of copper(I) to disproportionation in these media has permitted the study of the reduction of CoF(NH3)52+ and Co(HCOO)(NH3)52+ in range of solvents over a number of temperatures with a precision not possible in previous studies in water. The results are consistent with an inner-sphere mechanism in which the copper(I) reductant is preferentially solvated by dimethyl sulfoxide to the exclusion of water in mixed solvents.

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