On the magnetic properties of some distorted octahedral high-spin iron(II) complexes

1971 ◽  
pp. 2956 ◽  
Author(s):  
G. J. Long ◽  
W. A. Baker
Keyword(s):  
Magnetic Properties ◽  
High Spin ◽  
Distorted Octahedral ◽  
High Spin Iron

Magnetic properties and electronic structure of high spin iron(III) porphyrins

1983 ◽  
Vol 78 (3) ◽  
pp. 1453-1458 ◽  
Author(s):  
Roshun Birdy ◽  
D. V. Behere ◽  
S. Mitra
Keyword(s):  
Magnetic Properties ◽  
Electronic Structure ◽  
High Spin ◽  
High Spin Iron

scholarly journals A new mononuclear neutral high-spin iron(III) complex with the different tridentate ligands 5-bromosalicylaldehyde (pyridin-2-yl)hydrazone and 5-bromosalicylaldehyde thiosemicarbazone

2018 ◽  
Vol 74 (2) ◽  
pp. 252-255 ◽  
Author(s):  
Yun Zhao ◽  
Xiao-Feng Shen ◽  
Li-Fang Zhang
Keyword(s):  
High Spin ◽  
Magnetic Measurements ◽  
High Spin State ◽  
Mononuclear Complex ◽  
Monoclinic Space Group ◽  
Coordination Geometry ◽  
Tridentate Ligands ◽  
Complex Molecules ◽  
Distorted Octahedral ◽  
High Spin Iron

The title neutral mononuclear complex, [1-(5-bromo-2-oxidobenzylidene)thiosemicarbazidato](4-bromo-2-{[2-(pyridin-2-yl)hydrazinylidene]methyl}phenolato)iron(III), [Fe(C8H6BrN3OS)(C12H9BrN3O)] (I), crystallizes in the monoclinic space group C 2/c and has two different planar tridentate ligands. The central FeIII ion is coordinated to three N, two O and one S atom, forming a distorted octahedral FeN3O2S coordination geometry. In the crystal, the complex molecules are linked by N—H...O and N—H...N hydrogen bonds and π–π interactions into layers parallel to (100). Magnetic measurements show that the central FeIII ion is in the high-spin state; this is also supported by the bond distances around the FeIII ion.

New high-spin iron complexes based on bis(imino)acenaphthenes (BIAN): synthesis, structure, and magnetic properties

2013 ◽  
Vol 62 (10) ◽  
pp. 2122-2131 ◽  
Author(s):  
I. L. Fedushkin ◽  
A. A. Skatova ◽  
N. M. Khvoinova ◽  
A. N. Lukoyanov ◽  
G. K. Fukin ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
High Spin ◽  
Iron Complexes ◽  
High Spin Iron

Synthetic, Structural, and Spectroscopic Characterization of a Novel Family of High-Spin Iron(II) [(β-Diketiminate)(phosphanylphosphido)] Complexes

2017 ◽  
Vol 56 (18) ◽  
pp. 11030-11042 ◽  
Author(s):  
Rafał Grubba ◽  
Kinga Kaniewska ◽  
Łukasz Ponikiewski ◽  
Beata Cristóvão ◽  
Wiesława Ferenc ◽  
...  
Keyword(s):  
High Spin ◽  
Spectroscopic Characterization ◽  
High Spin Iron
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