Intramolecular aromatic hydroxylation via irradiation of pyridine N-oxide derivatives

1978 ◽  
pp. 853 ◽  
Author(s):  
Peter G. Sammes ◽  
Guido Serra-Errante ◽  
Alan C. Tinker
Keyword(s):  
Aromatic Hydroxylation

Unmasking Steps in Intramolecular Aromatic Hydroxylation by a Synthetic Nonheme Oxoiron(IV) Complex

2021 ◽  
Author(s):  
Lawrence Que ◽  
Yuan Sheng ◽  
Chase S. Abelson ◽  
Jai Prakash ◽  
Apparao Draksharapu ◽  
...  
Keyword(s):  
Aromatic Hydroxylation

scholarly journals Aromatic Hydroxylation of Indan by o-Xylene-Degrading Rhodococcus sp. Strain DK17

2009 ◽  
Vol 76 (1) ◽  
pp. 375-377 ◽  
Author(s):  
Dockyu Kim ◽  
Choong Hwan Lee ◽  
Jung Nam Choi ◽  
Ki Young Choi ◽  
Gerben J. Zylstra ◽  
...  
Keyword(s):  
Reverse Transcription ◽  
Ring Cleavage ◽  
Growth Substrate ◽  
Aromatic Moiety ◽  
Reverse Transcription Pcr ◽  
Aromatic Hydroxylation ◽  
Rhodococcus Sp

ABSTRACT The metabolically versatile Rhodococcus sp. strain DK17 utilizes indan as a growth substrate via the o-xylene pathway. Metabolite and reverse transcription-PCR analyses indicate that o-xylene dioxygenase hydroxylates indan at the 4,5 position of the aromatic moiety to form cis-indan-4,5-dihydrodiol, which is dehydrogenated to 4,5-indandiol by a dehydrogenase. 4,5-Indandiol undergoes ring cleavage by a meta-cleavage dioxygenase.

Mechanistic Insight into the Aromatic Hydroxylation by High-Valent Iron(IV)-oxo Porphyrin π-Cation Radical Complexes

2007 ◽  
Vol 72 (16) ◽  
pp. 6301-6304 ◽  
Author(s):  
Min-Jung Kang ◽  
Woon Ju Song ◽  
Ah-Rim Han ◽  
Young S. Choi ◽  
Ho G. Jang ◽  
...  
Keyword(s):  
Cation Radical ◽  
Mechanistic Insight ◽  
Aromatic Hydroxylation ◽  
High Valent ◽  
Insight Into

Different Geometric Requirements for Cytochrome P450-Catalyzed Aliphatic Versus Aromatic Hydroxylation Results in Chemoselective Oxidation

ACS Catalysis ◽  
2022 ◽  
pp. 1258-1267
Author(s):  
Tom Coleman ◽  
Alicia M. Kirk ◽  
Joel H. Z. Lee ◽  
Daniel Z. Doherty ◽  
John B. Bruning ◽  
...  
Keyword(s):  
Cytochrome P450 ◽  
Aromatic Hydroxylation

Synthesis of (NHC)Pd(salicylaldimine)Cl complexes through template-directed ortho-aromatic metaloxylation of NHC–palladacycles derived from arylimines

2017 ◽  
Vol 46 (15) ◽  
pp. 5003-5007 ◽  
Author(s):  
Jin Yang
Keyword(s):  
Butyl Hydroperoxide ◽  
Catalytic Activities ◽  
Aromatic Hydroxylation

NHC–palladacycles were ortho-aromatic metaloxylated in the presence of tert-butyl hydroperoxide, affording (NHC)Pd(salicylaldimine)Cl complexes. Furthermore, they also showed efficient catalytic activities toward the ortho-aromatic hydroxylation of arylimines.

AROMATIC HYDROXYLATION OF 2,4,6-TRIDEUTERIOTOLUENE BY O(3P) ATOMS WITH THE NIH SHIFT OF DEUTERIUM

1978 ◽  
Vol 7 (5) ◽  
pp. 467-470 ◽  
Author(s):  
Akira Hori ◽  
Hiroyuki Matsumoto ◽  
Setsuo Takamuku ◽  
Hiroshi Sakurai
Keyword(s):  
Aromatic Hydroxylation
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