Cyanoanthracene-sensitized photooxidations of N,N-dibenzylhydroxylamine and its derivatives: free-energy dependence of back electron-transfer rates within geminate radical ion pairs

1994 ◽  
pp. 2515 ◽  
Author(s):  
Tadamitsu Sakurai ◽  
Mayumi Yokono ◽  
Kanako Komiya ◽  
Yasuo Masuda ◽  
Hiroyasu Inoue
Keyword(s):  
Electron Transfer ◽  
Free Energy ◽  
Energy Dependence ◽  
Ion Pairs ◽  
Transfer Rates ◽  
Back Electron Transfer

Gaussian Free-Energy Dependence of Electron-Transfer Rates in Iridium Complexes

Science ◽  
1990 ◽  
Vol 247 (4946) ◽  
pp. 1069-1071 ◽  
Author(s):  
L. S. Fox ◽  
M. Kozik ◽  
J. R. Winkler ◽  
H. B. Gray
Keyword(s):  
Electron Transfer ◽  
Free Energy ◽  
Energy Dependence ◽  
Iridium Complexes ◽  
Transfer Rates

Diffusion of Solvent-Separated Ion Pairs Controls Back Electron Transfer Rate in Graphene Quantum Dots

2018 ◽  
Vol 122 (28) ◽  
pp. 15819-15825 ◽  
Author(s):  
Ayan Bhattacharyya ◽  
Soumalya Mukherjee ◽  
Anju Chadha ◽  
Edamana Prasad
Keyword(s):  
Quantum Dots ◽  
Electron Transfer ◽  
Transfer Rate ◽  
Ion Pairs ◽  
Graphene Quantum Dots ◽  
Electron Transfer Rate ◽  
Back Electron Transfer

scholarly journals Electronic and spatial control over the formation of transient ion pairs during photoinduced electron transfer between proflavine–amine systems in a subpicosecond time regime

RSC Advances ◽  
2017 ◽  
Vol 7 (25) ◽  
pp. 15149-15157 ◽  
Author(s):  
Chaitrali Sengupta ◽  
Piyali Mitra ◽  
Banabithi Koley Seth ◽  
Debabrata Mandal ◽  
Samita Basu
Keyword(s):  
Physical Chemistry ◽  
Electron Transfer ◽  
Free Energy ◽  
Photoinduced Electron Transfer ◽  
Ion Pairs ◽  
Spatial Control ◽  
Rate Of Reaction ◽  
Reaction Free Energy ◽  
Time Regime

Probing photoinduced electron transfer (PET) in solution in terms of rate of reaction and reaction free energy is a great challenge in physical chemistry.

Free energy-dependence of the electronic factor in biological long-range electron transfer

1989 ◽  
Vol 111 (4) ◽  
pp. 1315-1319 ◽  
Author(s):  
Kurt V. Mikkelsen ◽  
Jens Ulstrup ◽  
Merab G. Zakaraya
Keyword(s):  
Electron Transfer ◽  
Free Energy ◽  
Long Range ◽  
Energy Dependence ◽  
Electronic Factor
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