Luche reduction of enones using cerium trichloride

10.1039/sp22 ◽  
2001 ◽  
Author(s):  
zac etheridge
Keyword(s):  
Cerium Trichloride

ChemInform Abstract: The Reaction of Lithio-alkyl-isoxazoles with Acid Chlorides in the Presence of Cerium Trichloride.

1986 ◽  
Vol 17 (52) ◽  
Author(s):  
N. R. NATALE ◽  
S. G. YOCKLOVICH ◽  
B. M. MALLET
Keyword(s):  
Acid Chlorides ◽  
Cerium Trichloride

The Phase Diagram of the Cerium-Cerium Trichloride System

1959 ◽  
Vol 63 (7) ◽  
pp. 1110-1112 ◽  
Author(s):  
G. W. Mellors ◽  
S. Senderoff
Keyword(s):  
Phase Diagram ◽  
Cerium Trichloride

SOLUTIONS OF METALS IN MOLTEN SALTS CERIUM IN CERIUM TRICHLORIDE

1960 ◽  
Vol 64 (9) ◽  
pp. 1344-1344 ◽  
Author(s):  
H. R. Bronstein ◽  
A. S. Dworkin ◽  
M. A. Bredig
Keyword(s):  
Molten Salts ◽  
Cerium Trichloride

Laser emission at 1.065 μm from neodymium‐doped anhydrous cerium trichloride at room temperature

1974 ◽  
Vol 24 (1) ◽  
pp. 10-13 ◽  
Author(s):  
S. Singh ◽  
L. G. Van Uitert ◽  
J. R. Potopowicz ◽  
W. H. Grodkiewicz
Keyword(s):  
Room Temperature ◽  
Laser Emission ◽  
Cerium Trichloride

ChemInform Abstract: REDUCTION OF NATURAL ENONES IN THE PRESENCE OF CERIUM TRICHLORIDE

1978 ◽  
Vol 9 (45) ◽  
Author(s):  
J.-L. LUCHE ◽  
L. RODRIGUEZ-HAHN ◽  
P. CRABBE
Keyword(s):  
Cerium Trichloride

Protection of Zn–Ti–Cu alloy by cerium trichloride as corrosion inhibitor

2005 ◽  
Vol 200 (7) ◽  
pp. 2085-2091 ◽  
Author(s):  
M.A. Arenas ◽  
J. de Damborenea
Keyword(s):  
Corrosion Inhibitor ◽  
Cu Alloy ◽  
Cerium Trichloride

Synthesis of cedranoid sesquiterpenes. V. The biotols

1988 ◽  
Vol 66 (11) ◽  
pp. 2805-2815 ◽  
Author(s):  
Peter Yates ◽  
Rupinder S. Grewal ◽  
Peter C. Hayes ◽  
Jeffery F. Sawyer
Keyword(s):  
Hydrogen Chloride ◽  
Hydrogen Fluoride ◽  
Sodium Borohydride ◽  
Lithium Aluminum Hydride ◽  
Aluminum Hydride ◽  
Butyl Alcohol ◽  
Lithium Aluminum ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Cerium Trichloride

Reduction of dimethyl 3-hydroxy-4,4,8-trimethyl-6-oxo-cis-bicyclo[3.3.0]octa-2,7-diene-1,2-dicarboxylate (8) with lithium and ammonia gives dimethyl 3-hydroxy-4,4,exo-8-trimethyl-6-oxo-cis-bicyclo[3.3.0]oct-2-ene-1,2-dicarboxylate (9), which on acetylation, reduction with sodium borohydride, and methanolysis gives dimethyl 3,exo-6-dihydroxy-4,4,exo-8-trimethyl-cis-bicyclo[3.3.0]oct-2-ene-1,2-dicarboxylate (12). This on 2-decarbomethoxylation followed by treatment with lithium acetylide in the presence of cerium trichloride gives methyl 3-ethynyl-3,exo-6-dihydroxy-4,4,exo-8-trimethyl-cis-bicyclo[3.3.0]octane-1-carboxylate (21), which on hydration, diacetylation, and treatment with tri-n-butyltin hydride and azoisobutyronitrile is converted to methyl exo-6-acetoxy-3-acetyl-4,4,exo-8-trimethyl-cis-bicyclo[3.3.0]octane-1-carboxylate (31). Methanolysis of 31. tert-butyldimethylsilylation, and reaction with potassium tert-butoxide in tert-butyl alcohol gives exo-4-tert-butyldimethylsilyloxy-exo-2,6,6-trimethyl[5.3.11,5]undecane-8,10-dione (35). This on treatment with lithium aluminum hydride followed by oxidation and hydrogenation provides the corresponding 10-deoxo compound, 39. Reaction of this with methyllithium, dehydration, and desilylation with hydrogen fluoride in acetonitrile gives a mixture of (±)-α-biotol (1) and (±)-β-biotol (2); desilylation with hydrogen chloride in methanol gives solely (±)-1.

ChemInform Abstract: Lithium Benzenetellurolate-Induced Reformatsky-Type Reaction in the Presence of Cerium Trichloride.

ChemInform ◽  
2010 ◽  
Vol 24 (51) ◽  
pp. no-no
Author(s):  
S. FUKUZAWA ◽  
K. HIRAI
Keyword(s):  
Type Reaction ◽  
Cerium Trichloride
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