Влияние микротрещин на коэффициент Пуассона при пластическом деформировании аустенитной стали

We researched the influence of damage accumulation on the Poisson's ratio measured by echo-pulse acoustic method during plastic deformation of 12Kh18N10T steel. On the basis of the obtained experimental data we calculated the partial contributions to the change in the Poisson's ratio of damage accumulation and separation of the strain induced martensite phase. The characteristics of stable cracks forming near strain martensite particles at small degrees of plastic strain have been analyzed by computer simulation. The theoretical dependence of the change in the Poisson's ratio due to crack formation during plastic deformation has been constructed. A good agreement between the experimental data and theoretical calculations has been obtained.

Application of Multi-Element Targets for the Formation of High Entropy Coatings

The development of modern technologies in various industries cannot be imagined without the development and use of new materials, including new highly entropic alloys (HEA) and coatings based on them, as more advanced in terms of performance compared to traditional materials and coatings. Methods for producing various highly entropic alloys are described in many literature. Almost all such technologies at the moment cannot be applicable in the mass production of parts due to the high cost and lack of appropriate infrastructure and production technologies. However, obtaining coatings formed on the basis of highly entropic alloys for various parts of mechanisms and machines is currently a highly promising direction in improving the operational properties of work surfaces. The goal of this work is to create highly entropic coatings obtained by magnetron sputtering of special multicomponent targets. The paper shows the possibility of synthesis of coatings of the predicted composition and properties. A coating based on a matrix target made of 12Kh18N10T steel with pressed multicomponent Cr-Ni-Zr-Ti-Cu pellets was synthesized. The elemental composition of the coating and its properties were determined, the microhardness was measured, and the functional properties were established.

Sub-Microstructure of Surface and Subsurface Layers after Electrical Discharge Machining Structural Materials in Water

The material removal mechanism, submicrostructure of surface and subsurface layers, nanotransformations occurred in surface and subsurface layers during electrical discharge machining two structural materials such as anti-corrosion X10CrNiTi18-10 (12kH18N10T) steel of austenite class and 2024 (D16) duralumin in a deionized water medium were researched. The machining was conducted using a brass tool of 0.25 mm in diameter. The measured discharge gap is 45–60 µm for X10CrNiTi18-10 (12kH18N10T) steel and 105–120 µm for 2024 (D16) duralumin. Surface roughness parameters are arithmetic mean deviation (Ra) of 4.61 µm, 10-point height (Rz) of 28.73 µm, maximum peak-to-valley height (Rtm) of 29.50 µm, mean spacing between peaks (Sm) of 18.0 µm for steel; Ra of 5.41 µm, Rz of 35.29 µm, Rtm of 43.17 µm, Sm of 30.0 µm for duralumin. The recast layer with adsorbed components of the wire tool electrode and carbides was observed up to the depth of 4–6 µm for steel and 2.5–4 µm for duralumin. The Levenberg–Marquardt algorithm was used to mathematically interpolate the dependence of the interelectrode gap on the electrical resistance of the material. The observed microstructures provide grounding on the nature of electrical wear and nanomodification of the obtained surfaces.

Elemental and Thermochemical Analyses of Materials after Electrical Discharge Machining in Water: Focus on Ni and Zn

The mechanism of the material destruction under discharge pulses and material removal mechanism based on the thermochemical nature of the electrical erosion during electrical discharge machining of conductive materials were researched. The experiments were conducted for two structural materials used in the aerospace industry, namely austenite anticorrosion X10CrNiTi18-10 (12kH18N10T) steel and 2024 (D16) duralumin, machined by a brass tool of 0.25 mm in diameter in a deionized water medium. The optimized wire electrical discharge machining factors, measured discharge gaps (recommended offset is 170–175 µm and 195–199 µm, respectively), X-ray photoelectron spectroscopy for both types of materials are reported. Elemental analysis showed the presence of metallic Zn, CuO, iron oxides, chromium oxides, and 58.07% carbides (precipitation and normal atmospheric contamination) for steel and the presence of metallic Zn, CuO, ZnO, aluminum oxide, and 40.37% carbides (contamination) for duralumin. For the first time, calculating the thermochemistry parameters for reactions of Zn(OH)2, ZnO, and NiO formation was produced. The ability of Ni of chrome–nickel steel to interact with Zn of brass electrode was thermochemically proved. The standard enthalpy of the Ni5Zn21 intermetallic compound formation (erosion dust) ΔH0298 is −225.96 kJ/mol; the entropy of the crystalline phase Scint is 424.64 J/(mol·K).

Influence of dispersed particles of tungsten carbide on the microstructure of 12Kh18N10T steel obtained by centrifugal casting

The development of new technologies in various industries, such as fast neuron reactors, require a new level of operational properties from steels and raise the issues of resistance to neutron radiation, radiation swelling, embrittlement and creep, and the level of residual activation. The principal way to increase these properties is to adjust the chemical composition, and rearrange the crystal structure of the metal. The authors propose to achieve this by introducing finely dispersed particles into the melt and controlled by them to “reinforce” the crystal lattice, grinding the metal structure. During the work, using the FactSage software package, thermodynamic modeling of the interaction of dispersed particles with a 18Х18Н10T steel melt was carried out, showing that the particles will interact with the metal melt, which can lead to their complete dissociation, and at the next stage of crystallization, regardless of the degree of dissolution of tungsten carbide, the formation of carbide phases based on titanium carbide with an FSS structure, as well as a carbide phase based on chromium carbide with the formula M23C3, will become. According to the simulation parameters, experiments were conducted, experimental blanks with different contents of the introduced tungsten carbide were obtained, and heat treatment was carried out. The study of microstructures showed that the introduced particles of tungsten carbide completely dissociate when interacting with a metal melt and contribute to an increase in ferrite in the microstructure of the workpiece. Studies of microhardness confi rmed the significant effect of the introduced carbide on the properties of the material: the maximum values of microhardness are achieved at a high concentration of refractory particles in the areas of their maximum concentration (outer edge of the workpieces). Carrying out heat treatment reduces microhardness, while aligning the gradient of properties with the volume of castings. This work was financially supported by the Ministry of Science and Higher Education of the Russian Federation within the framework of the federal target program under Agreement No. 075-15-2019-1711 (internal number 05.608.21.0276) dated December 04, 2019 (unique project identifier RFMEFI60819X0276).