Periodic binary codes with zero and small time sidelobe levels

2006 ◽  
Vol 153 (6) ◽  
pp. 482 ◽  
Author(s):  
M. Shinriki ◽  
H. Takase ◽  
H. Susaki
Keyword(s):  
2020 ◽  
Author(s):  
Xingxing Wu ◽  
Reto M. Witzig ◽  
Rodolphe Beaud ◽  
Christian Fischer ◽  
Daniel Häussinger ◽  
...  

Governing higher-order stereogenicity is a long-standing goal in stereoselective catalysis, because it allows to achieve selectivity for more than a twofold number of stereoisomers per stereogenic unit. Current methods warrant control over the power of two stereoisomers and the configurations are routinely assigned using the descriptors ( R ) and ( S ), or related binary codes. In contrast, conformational analysis ranges beyond this dualistic treatment of stereoisomerism, which constitutes an unmet challenge for catalyst stereocontrolled processes. Herein, we now report that sixfold stereogenicity can be governed by stereoselective catalysis. By controlling a configurationally stable stereogenic axis with six large rotational barriers, a catalytic [2+2+2]-cyclotrimerization selectively governs the formation of one out of six stereoisomers with up to 0:0:2:98:0:0 stereocontrol. The underpinnings of conformational analysis and stereoselective catalysis are thereby conceptually reunited. Novel molecular architectures featuring distinct chemical topologies and unexplored chemical designs are anticipated from catalystcontrol over higher-order stereogenicities


Author(s):  
Gregory E. Coxson ◽  
Jon C. Russo ◽  
Angeline Luther

2021 ◽  
Vol 344 (3) ◽  
pp. 112261
Author(s):  
Zihui Liu
Keyword(s):  

2021 ◽  
pp. 107754632110037
Author(s):  
Sun Jiaojiao ◽  
Xia Lei ◽  
Ying Zuguang ◽  
Huan Ronghua ◽  
Zhu Weiqiu

A closed-loop controlled system usually consists of the main structure, sensors, and actuators. The dynamics of sensors and actuators may influence the motion of the main structure. This article presents an analytical study on the first-passage reliability of a nonlinear stochastic controlled system under the consideration of the dynamics of sensors and actuators. The coupled dynamic equations of the controlled systems with sensors and actuators are first given, which are further integrated into a controlled, randomly excited, dissipated Hamiltonian system. By applying the stochastic averaging method for quasi-Hamiltonian systems, a one-dimensional averaged differential equation for the Hamiltonian function is obtained. The backward Kolmogorov equation associated with the averaged equation is then derived for the first-passage reliability analysis, from which the approximate reliability function and probability density of first-passage time are obtained. The accuracy of the proposed procedure is demonstrated by an example. A comparative analysis of the reliability of the system with/without sensors and actuators is carried out, which indicates that ignoring sensors and actuators will make underestimation of the reliability of the closed-loop system with small time. However, when time increases, there appears the opposite trend. Our findings provide a reference for control strategy design.


2021 ◽  
Vol 110 ◽  
pp. 102583
Author(s):  
Elona Fetahu ◽  
Oguz Yilmaz

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