Oxidative C-H Acyloxylation of Acetone with Carboxylic Acids under Iodine Catalysis
Keyword(s):
Iodine catalyzed oxidative C(sp3)-H acyloxylation of acetone with carboxylic acids has been developed. The method employs an iodide as catalyst and sodium chlorite as oxidant. Substituted benzoic acids, naphthoic acids and hetero-aromatic carboxylic acids can be used, and 2-oxopropyl carboxylates are obtained with good to excellent yields.
1997 ◽
Vol 10
(6)
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pp. 466-472
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1984 ◽
Vol 49
(1)
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pp. 179-189
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2010 ◽
Vol 90
(2)
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pp. 137-149
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2003 ◽
Vol 134
(4)
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pp. 533-538
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1974 ◽
Vol 29
(9-10)
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pp. 469-474
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