First Total Synthesis of 7-Isovaleryloxy-8-methoxygirinimbine
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We describe the first total synthesis of the pyrano[3,2-a]carbazole alkaloid 7-isovaleryloxy-8-methoxygirinimbine, using a palladium(II)-catalyzed double C–H-bond activation for construction of the carbazole framework and a phenylboronic acid catalyzed annulation of the pyran ring as key steps.
2014 ◽
Vol 20
(28)
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pp. 8536-8540
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2010 ◽
Vol 65
(4)
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pp. 445-451
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2017 ◽
Vol 15
(44)
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pp. 9408-9414
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