Synthesis of a Zeolitic Imidazolate–Zinc Metal–Organic Framework and the Combination of its Catalytic Properties with 2,2,2-Trifluoroethanol for N-Formylation

Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1593-1596 ◽  
Author(s):  
Sadegh Rostamnia ◽  
Asadollah Hassankhani ◽  
Hassan Alamgholiloo ◽  
Reza Banaei
Keyword(s):  
Formic Acid ◽  
Heterogeneous Catalyst ◽  
Catalytic Properties ◽  
Metal Organic Framework ◽  
Zeolitic Imidazolate Framework ◽  
Zinc Metal ◽  
Metal Organic ◽  
Organic Framework

A novel protocol is reported for the N-formylation of amines with formic acid by using the nanoporous zeolitic imidazolate framework ZIF-8 as a heterogeneous catalyst in 2,2,2-trifluoroethanol.

Catalytic properties of a cobalt metal–organic framework with a zwitterionic ligand synthesized in situ

2017 ◽  
Vol 46 (45) ◽  
pp. 15698-15703 ◽  
Author(s):  
T. A. Grigolo ◽  
S. D. de Campos ◽  
F. Manarin ◽  
G. V. Botteselle ◽  
P. Brandão ◽  
...  
Keyword(s):  
Heterogeneous Catalyst ◽  
Catalytic Properties ◽  
Metal Organic Framework ◽  
Cobalt Metal ◽  
Metal Organic ◽  
Organic Framework

Highly stable Co-MOF with in situ synthesized ligand as heterogeneous catalyst.

Metal–organic framework-derived CoSe2/(NiCo)Se2 box-in-box hollow nanocubes with enhanced electrochemical properties for sodium-ion storage and hydrogen evolution

2017 ◽  
Vol 5 (35) ◽  
pp. 18823-18830 ◽  
Author(s):  
Seung-Keun Park ◽  
Jin Koo Kim ◽  
Yun Chan Kang
Keyword(s):  
Electrochemical Properties ◽  
Hydrogen Evolution ◽  
Metal Organic Framework ◽  
Sodium Ion ◽  
Zeolitic Imidazolate Framework ◽  
Box Structures ◽  
Ion Storage ◽  
Metal Organic ◽  
Sodium Ion Storage ◽  
Organic Framework

Multishell structured metal selenide nanocubes, namely, Co/(NiCo)Se2 box-in-box structures with different shell compositions, were successfully synthesized by applying zeolitic imidazolate framework-67 (ZIF-67) as a template.

A new superacid hafnium-based metal–organic framework as a highly active heterogeneous catalyst for the synthesis of benzoxazoles under solvent-free conditions

2017 ◽  
Vol 7 (19) ◽  
pp. 4346-4350 ◽  
Author(s):  
Linh H. T. Nguyen ◽  
The T. Nguyen ◽  
Ha L. Nguyen ◽  
Tan L. H. Doan ◽  
Phuong Hoang Tran
Keyword(s):  
Heterogeneous Catalyst ◽  
Metal Organic Framework ◽  
Solvent Free ◽  
Highly Active ◽  
Solvent Free Conditions ◽  
Metal Organic ◽  
Efficient Heterogeneous Catalyst ◽  
Organic Framework

A new superacid Hf-based MOF, termed VNU-11-P-SO4, was used as an efficient heterogeneous catalyst for solvent-free 2-arylbenzoxazole synthesis.

Metal–organic framework mediated expeditious synthesis of benzimidazole and benzothiazole derivatives through an oxidative cyclization pathway

2020 ◽  
Vol 44 (3) ◽  
pp. 1021-1027
Author(s):  
Velayudham Sankar ◽  
Peramaiah Karthik ◽  
Bernaurdshaw Neppolian ◽  
Bitragunta Sivakumar
Keyword(s):  
Heterogeneous Catalyst ◽  
Good Yield ◽  
Metal Organic Framework ◽  
Oxidative Cyclization ◽  
Facile Synthesis ◽  
Benzothiazole Derivatives ◽  
Metal Organic ◽  
Organic Framework

Herein, we report facile synthesis of various benzimidazoles and benzothiazoles by using the NH2-MIL-125(Ti) MOF as an efficient oxidant-free heterogeneous catalyst with good yield.

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