Structure of nonuniform fluid mixtures: A self-consistent density-functional approach

2002 ◽  
Vol 117 (19) ◽  
pp. 8933-8937 ◽  
Author(s):  
Chandra N. Patra ◽  
Swapan K. Ghosh
Keyword(s):  
Density Functional ◽  
Functional Approach ◽  
Fluid Mixtures ◽  
Nonuniform Fluid ◽  
Self Consistent

Self-Consistent Density Functional Approach to a Metal/Electrolyte Solution Interface

1984 ◽  
Vol 39 (11) ◽  
pp. 1122-1133 ◽  
Author(s):  
A. A. Kornyshev ◽  
M. B. Partenskii ◽  
W. Schmickler
Keyword(s):  
Electrolyte Solution ◽  
Free Electron ◽  
Density Functional ◽  
Functional Approach ◽  
Electron Cloud ◽  
System Parameters ◽  
Solution Interface ◽  
Self Consistent ◽  
Concentrated Solution ◽  
Solvent Molecules

Two models for a plane interface between a free electron metal and a concentrated solution of a surface inactive electrolyte are treated fully self-consistently, taking into account both the polarizability of the metallic electron cloud and the reorientation of solvent molecules. The interfacial capacity is calculated as a function of the electrode charge, and its dependence on various system parameters is investigated. Some conclusions on the structure of the interface are drawn from a comparison between our results and experimentally observed trends.

Sign in / Sign up

Export Citation Format

Share Document