scholarly journals Erratum: Distribution Functions of a Fluid in an External Potential Field. Application to Physical Adsorption

1961 ◽  
Vol 34 (3) ◽  
pp. 1067-1067 ◽  
Author(s):  
William A. Steele ◽  
Marvin Ross
2021 ◽  
Vol 29 (1) ◽  
pp. 21-28
Author(s):  
A. I. Sokolovsky ◽  
S. A. Sokolovsky

On the base of the Boltzmann kinetic equation, hydrodynamics of a dilute gas in the presence of the strong external potential field is investigated. First of all, a gravitational field is meant, because the consistent development of hydrodynamics in this environment is of great practical importance. In the present paper it is assumed that it is possible to neglect the influence of the field on the particle collisions. The study is based on the Chapman–Enskog method in a Bogolyubov’s formulation, which uses the idea of the functional hypothesis. Consideration is limited to steady gas states, which are subjected to a simpler experimental study. Chemical potential μ0 of the gas at the point where the external field has zero value and its temperature T are selected as the reduced description parameters of the system. In equilibrium, in the presence of the field, these values do not depend on the coordinates. It is assumed that in thehydrodynamic states T and μ0 are weakly dependent on the coordinates and therefore their gradients, considered on the scale of the free path length of the gas, are small. The kinetic equation, accounting for the functional hypothesis, gives an integro-differential equation for a gas distribution function at the hydrodynamic stage of evolution. This equation is solved in perturbation theory in gradients of T and μ0. The main approximation is analyzed for possibility of the system to be in a local equilibrium by means of comparing it with an equilibrium distribution function. Next, the distribution function is calculated in the first approximation in gradients and it is expressed in terms of solutions Ap , Bp of some first kind integral Fredholm equations. An approach to the approximate solution of these equations is discussed. The found distribution function is used to calculate the fluxes of the number of gas particles and their energy in the first order in gradients T and μ0 . Kinetic coefficients, which describe the structure of these fluxes, are introduced. Matrix elements of the operator of the linearized collision integral (integral brackets) are used for their research. It is a question of validity of the principle of symmetry of kinetic coefficients and definition of their signs.


2005 ◽  
Vol 38 (4) ◽  
pp. 37-38
Author(s):  
Henk J. Ritsema van Eck ◽  
Gerard van Herpen ◽  
Jan H. van Bemmel ◽  
Jan A. Kors

2016 ◽  
Vol 30 (14) ◽  
pp. 1650116
Author(s):  
Hai Pang ◽  
Sen Wu

In this paper, we introduce a method for analytically calculating the Fermi energy. As an example, we study the hard-sphere (HS) gas, the gas in porous media and the gas in an external potential field or curved background. These examples are valuable for studying the spectral structure of a real gas.


1994 ◽  
Vol 41 (1) ◽  
pp. 291 ◽  
Author(s):  
M.C. Schiewe ◽  
N.M. Loskutoff ◽  
B.S. Durrant ◽  
L.A. Johnston ◽  
D.L. Armstrong ◽  
...  

1985 ◽  
Vol 2 (4) ◽  
pp. 253-262 ◽  
Author(s):  
E. J. Bottani ◽  
L. E. Cascarini De Torre

Different models which describe CO2 physisorption on a graphitized carbon black are analysed in the range 194·7 to 273·2 K. They are related to the thermodynamic functions and to adsorption energy distribution functions, which are obtained starting from experimental adsorption isotherms. This calculation, previously presented, is based on an extension of the Ross and Olivier method.


1964 ◽  
Vol 17 (3) ◽  
pp. 259 ◽  
Author(s):  
JA Barker

Previous results on the statistical mechanics of almost one-dimensional systems of molecules or atoms are generalized to allow for the presence of a longitudinally varying external potential energy field. Methods for calculating the local density and higher order distribution functions are described. Equations valid for mixtures of molecules of different kinds are derived. Possible applications of the theor{jtical results are indicated and a detailed application to the twodimensional hard disk system is described.


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