Thermodynamic Functions of Carbon Tetrachloride and Monochloride

The perturbation treatment of the orientational forces between non-spherical molecules proposed by Cook & Rowlinson (1953) is extended to mixtures by using the theory of solutions put forward by Longuet-Higgins (1951). The thermodynamic functions and the equation of state of such mixtures are expressed in terms of the intermolecular forces and the properties of one pure component. Expressions are derived for the excess (or non-ideal) thermodynamic functions which are compared with the experimental results on the four solutions, benzene+ cyclohexane , benzene+carbon tetrachloride, benzene + ethylene dychloride, and cyclohexane + carbon tetrachloride. The agreement between theory and experiment is improved by taking account of the orientational forces.

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ChemInform Abstract: EXCESS THERMODYNAMIC FUNCTIONS OF THE SYSTEMS ISOOCTANE + CARBON TETRACHLORIDE AND ISOOCTANE + CYCLOHEXANE

Chemischer Informationsdienst ◽

10.1002/chin.197345115 ◽

1973 ◽

Vol 4 (45) ◽

pp. no-no

Author(s):

S. V. SUBRAHMANYAM ◽

E. RAJAGOPAL

Keyword(s):

Carbon Tetrachloride ◽

Thermodynamic Functions ◽

Excess Thermodynamic Functions

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APPLICATION OF QUASI-LATTICE THEORY TO ALCOHOL – CARBON TETRACHLORIDE SYSTEMS

Canadian Journal of Chemistry ◽

10.1139/v63-043 ◽

1963 ◽

Vol 41 (2) ◽

pp. 278-286 ◽

Cited By ~ 34

Author(s):

B. Dacre ◽

G. C. Benson

Keyword(s):

Carbon Tetrachloride ◽

Thermodynamic Functions ◽

Lattice Theory ◽

Experimental Results ◽

Heats Of Mixing ◽

Excess Thermodynamic Functions

Values of heats of mixing are reported for methanol, n-butanol, and n-octanol with carbon tetrachloride at 25 °C. The experimental results are combined with data from other sources and an analysis of the excess thermodynamic functions for carbon tetrachloride solutions of methanol, ethanol, n-propanol, n-butanol, and n-octanol in terms of Barker's theory of solutions is described. The behavior of these systems can be reproduced fairly well by the Barker model.

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Liquid-Vapour Equilibria. I. The Systems Carbon Tetrachloride-cyclo-hexane and Water-Acetic Acid

Australian Journal of Chemistry ◽

10.1071/ch9500306 ◽

1950 ◽

Vol 3 (2) ◽

pp. 306 ◽

Cited By ~ 2

Author(s):

I Brown ◽

AH Ewald

Keyword(s):

Acetic Acid ◽

Carbon Tetrachloride ◽

Thermodynamic Functions ◽

Accurate Determination ◽

Chemical Potentials ◽

Equilibrium Data ◽

System Water

An apparatus for the accurate determination of liquid-vapour equilibria is described. Data obtained with it for the system carbon tetrachloride-cyclohexane at 70 �C. and the thermodynamic functions derived from these are shown to agree with the corresponding values determined by Scatchard, Wood, and Mochel(1). Equilibrium data of the system water-acetic acid have been measured at 760 mm. Hg, particular attention being given to high acetic acid concentrations. These results are compared with published values and the excess chemical potentials of the components have been calculated.

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