Ferroelectric BaTiO3/BaZrO3 superlattices: X-ray diffraction, Raman spectroscopy, and polarization hysteresis loops

2010 ◽  
Vol 108 (8) ◽  
pp. 084104 ◽  
Author(s):  
M. El Marssi ◽  
Y. Gagou ◽  
J. Belhadi ◽  
F. De Guerville ◽  
Yu. I. Yuzyuk ◽  
...  
Author(s):  
M. I. Samoylovich ◽  
А. F. Belyanin ◽  
A. S. Bagdasaryan

The article considers specific features of the formation of nanocomposites based on the lattice packing of SiO2 nanospheres (opal matrices) with clusters of titanium and iron compounds (FeTiO3, FeTi2O5, TiO2, Fe2O3) embedded into nanopores between spheres. For the formation of the nanocomposites samples of opal matrices with the sizes of single-domain regions > 0.1 mm3 were used. The diameter of the SiO2 nanospheres was ~260 nm. Nanocomposites with the volume > 1 cm3 and 10-15% of interspherical nanospacing filled by crystallites of titanium and iron compounds were obtained. The composition and structure of the nanocomposites were studied by electron microscopy, X-ray diffraction and Raman spectroscopy. The dependence of the composition of the synthesized materials on the conditions of their preparation is shown. Results of measurements of the frequency dependences (within the range 1 MHz - 3 GHz) of the magnetic and dielectric characteristics of the obtained nanostructures are presented. Hysteresis loops were studied for the obtained samples.


2005 ◽  
Vol 126 ◽  
pp. 101-105 ◽  
Author(s):  
B. Moulin ◽  
L. Hennet ◽  
D. Thiaudière ◽  
P. Melin ◽  
P. Simon

2009 ◽  
Vol 2009 ◽  
pp. 1-4 ◽  
Author(s):  
L. Bourja ◽  
B. Bakiz ◽  
A. Benlhachemi ◽  
M. Ezahri ◽  
J. C. Valmalette ◽  
...  

A series of ceramics samples belonging to theCeO2-Bi2O3phase system have been prepared via a coprecipitation route. The crystallized phases were obtained by heating the solid precursors at600∘Cfor 6 hours, then quenching the samples. X-ray diffraction analyses show that forx<0.20a solid solutionCe1−xBixO2−x/2with fluorine structure is formed. For x ranging between 0.25 and 0.7, a tetragonalβ′phase coexisting with the FCC solid solution is observed. For x ranging between 0.8 and 0.9, a new tetragonalβphase appears. Theβ′phase is postulated to be a superstructure of theβphase. Finally, close tox=1, the classical monoclinicα Bi2O3structure is observed. Raman spectroscopy confirms the existence of the phase changes as x varies between 0 and 1.


2021 ◽  
Vol 545 ◽  
pp. 152751
Author(s):  
Marie-Noëlle de Noirfontaine ◽  
Enrique Garcia-Caurel ◽  
Daniel Funes-Hernando ◽  
Mireille Courtial ◽  
Sandrine Tusseau-Nenez ◽  
...  

2012 ◽  
Vol 192 ◽  
pp. 356-359 ◽  
Author(s):  
Ye Wu ◽  
Qian Zhang ◽  
Xiang Wu ◽  
Shan Qin ◽  
Jing Liu

2009 ◽  
Vol 106 (3) ◽  
pp. 034108 ◽  
Author(s):  
H. Bouyanfif ◽  
J. Wolfman ◽  
M. El Marssi ◽  
Y. Yuzyuk ◽  
R. Bodeux ◽  
...  

2002 ◽  
Vol 198 (3-4) ◽  
pp. 485-493 ◽  
Author(s):  
Martin Kunz ◽  
Philippe Gillet ◽  
Guillaume Fiquet ◽  
Violaine Sautter ◽  
Heinz Graafsma ◽  
...  

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