Anisotropic orientation in molecular monolayers by infrared spectroscopy

1983 ◽  
Vol 78 (2) ◽  
pp. 946-952 ◽  
Author(s):  
J. F. Rabolt ◽  
F. C. Burns ◽  
N. E. Schlotter ◽  
J. D. Swalen
1968 ◽  
Vol 110 (4) ◽  
pp. 733-737 ◽  
Author(s):  
B. R. Malcolm

Molecular monolayers of poly-∈-benzyloxycarbonyl-l-lysine were studied at the air/water interface. Deuterium-exchange measurements and the surface area of the monolayer are consistent with a structure consisting of condensed ordered arrays of α-helices. Collapsed films removed from the surface and air-dried were examined by polarized infrared spectroscopy and electron diffraction and found to consist of molecules in the α-helical conformation. There is no indication of a conformational change during compression of the monolayer, and a series of transitions found in the force–area curve are interpreted as the consecutive formation of additional layers of molecules. Some of the factors that influence this almost perfect plastic behaviour are discussed.


2008 ◽  
Vol 112 (48) ◽  
pp. 12372-12377 ◽  
Author(s):  
Hong-Bo Liu ◽  
Nagaiyanallur V. Venkataraman ◽  
Tobias E. Bauert ◽  
Marcus Textor ◽  
Shou-Jun Xiao

1997 ◽  
Vol 90 (3) ◽  
pp. 495-497
Author(s):  
CLAUDIO ESPOSTI ◽  
FILIPPO TAMASSIA ◽  
CRISTINA PUZZARINI ◽  
RICCARDO TARRONI ◽  
ZDENEK ZELINGER

Agronomie ◽  
2001 ◽  
Vol 21 (2) ◽  
pp. 169-178 ◽  
Author(s):  
Giovanni Gigliotti ◽  
Pier Lodovico Giusquiani ◽  
Daniela Businelli

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