Greywater Treatment of Emerging Pollutant Linear Alkylbenzene Sulfonate By Adsorption With Leather Shave Waste Activated Carbon

This study aims to evaluate the use of leather shave waste activated carbon (ACLW) as an alternative for the treatment of wastewaters containing Linear Alkylbenzene Sulphonate (LAS). Batch adsorption tests were carried out (pH effect, isotherms, kinetics). The activated carbon was tested for its life cycle by desorption with solvents and it was also evaluated as a real wastewater treatment for bath greywater. Under the optimum pH of 2.5, the equilibrium isotherms correlated better with the Freundlich and Redlich-Peterson models, indicating a possible multilayer formation, and classifying the isotherm as having a high affinity. Adsorption was shown to be endothermic (∆H0 = +73.89 kJ mol-1), entropy driven (∆S0 = +0.46 kJ mol-1 K-1) and occurs spontaneously. The kinetic studies showed a best correlation with the pseudo-second order model, with activation energy of 27.5 kJ mol-1. The use of ethanol solution was effective for the regeneration of the adsorbent. The adsorption was applied in real wastewater, removing contaminants from bath greywater, especially anionic surfactants with up to 95% removal efficiency.

Ion-Specific and Solvent Effects on PDADMA–PSS Complexation and Multilayer Formation

Among various parameters that influence the formation of polyelectrolyte complexes and multilayers, special emphasis should be placed on ion-specific and solvent effects. In our study, we systematically examined the above-mentioned effects on poly(diallyldimethylammonium chloride) (PDADMACl)-sodium poly(4-styrenesulfonate) (NaPSS) complexation in solution and at the surface by means of dynamic light scattering, ellipsometry and atomic force microscopy measurements. As solvents, we used water and water/ethanol mixture. The obtained results confirm the importance of ion-specific and solvent effects on complexes prepared in solution, as well as on multilayers built up on a silica surface. The experiments in mixed solvent solution showed that at a higher ethanol mole fraction, the decrease in monomer titrant to titrand ratio, at which the increase in the size of complexes is observed, takes place. The difference between chloride and bromide ions was more pronounced at a higher mole fraction of ethanol and in the case of positive complex formation, suggesting that the larger amount of bromide ions could be condensed to the polycation chain. These findings are in accordance with the results we obtained for polyelectrolyte multilayers and could be helpful for designing polyelectrolyte multilayers with tuned properties needed for various applications, primarily in the field of biomedicine.

Equilibrium and Kinetic Study of Anionic and Cationic Pollutants Remediation by Limestone–Chitosan–Alginate Nanocomposite from Aqueous Solution

In this work, low-cost and readily available limestone was converted into nanolimestone chitosan and mixed with alginate powder and precipitate to form a triple nanocomposite, namely limestone—chitosan–alginate (NLS/Cs/Alg.), which was used as an adsorbent for the removal of brilliant green (BG) and Congo red (CR) dyes in aqueous solutions. The adsorption studies were conducted under varying parameters, including contact time, temperature, concentration, and pH. The NLS/Cs/Alg. was characterized by SEM, FTIR, BET, and TEM techniques. The SEM images revealed that the NLS/Cs/Alg. surface structure had interconnected pores, which could easily trap the pollutants. The BET analysis established the surface area to be 20.45 m2/g. The recorded maximum experimental adsorption capacities were 2250 and 2020 mg/g for CR and BG, respectively. The adsorption processes had a good fit to the kinetic pseudo second order, which suggests that the removal mechanism was controlled by physical adsorption. The CR and BG equilibrium data had a good fit for the Freundlich isotherm, suggesting that adsorption processes occurred on the heterogeneous surface with a multilayer formation on the NLS/Cs/Alg. at equilibrium. The enthalpy change (ΔH0) was 37.7 KJ mol−1 for CR and 8.71 KJ mol−1 for BG, while the entropy change (ΔS0) was 89.1 J K−1 mol−1 for CR and 79.1 J K−1 mol−1 BG, indicating that the adsorption process was endothermic and spontaneous in nature.

Swarming bacteria undergo localized dynamic phase transition to form stress-induced biofilms

Self-organized multicellular behaviors enable cells to adapt and tolerate stressors to a greater degree than isolated cells. However, whether and how cellular communities alter their collective behaviors adaptively upon exposure to stress is largely unclear. Here, we investigate this question using Bacillus subtilis, a model system for bacterial multicellularity. We discover that, upon exposure to a spatial gradient of kanamycin, swarming bacteria activate matrix genes and transit to biofilms. The initial stage of this transition is underpinned by a stress-induced multilayer formation, emerging from a biophysical mechanism reminiscent of motility-induced phase separation (MIPS). The physical nature of the process suggests that stressors which suppress the expansion of swarms would induce biofilm formation. Indeed, a simple physical barrier also induces a swarm-to-biofilm transition. Based on the gained insight, we propose a strategy of antibiotic treatment to inhibit the transition from swarms to biofilms by targeting the localized phase transition.

Predicting the outcomes of interpolyelectrolyte neutralization at surfaces on the basis of complexation experiments and vice versa

The study is carried out with the aim of establishing in which measure the outcomes of polyelectrolyte multilayer formation can be predicted on the basis of the results of complexation...

Marine electrical imaging reveals novel freshwater transport mechanism in Hawai‘i

Conventional hydrogeologic framework models used to compute ocean island sustainable yields and aquifer storage neglect the complexity of the nearshore and offshore submarine environment. However, the onshore aquifer at the island of Hawai‘i exhibits a notable volumetric discrepancy between high-elevation freshwater recharge and coastal discharge. In this study, we present a novel transport mechanism of freshwater moving from onshore to offshore through a multilayer formation of water-saturated layered basalts with interbedded low-permeability layers of ash/soil. Marine electromagnetic imaging reveals ∼35 km of laterally continuous resistive layers that extend to at least 4 km from west of Hawai‘i’s coastline, containing about 3.5 km3 of freshened water. We propose that this newly found transport mechanism of fresh groundwater may be the governing mechanism in other volcanic islands. In such a scenario, volcanic islands worldwide can use these renewable offshore reservoirs, considered more resilient to climate change-driven droughts, as new water resources.

Kinetics and Isotherm Modeling for the Treatment of Rubber Processing Effluent Using Iron (II) Sulphate Waste as a Coagulant

There is increasing concern to determine an alternative coagulant for treating industrial effluent with minimal environmental impact and operational cost. In this study, iron (II) sulphate heptahydrate (FeSO4·7H2O) waste, an industrial byproduct from a titanium oxide processing industry, was used as a coagulant for the removal of ammonia (NH3), chemical oxygen demand (COD), biochemical oxygen demand (BOD), and suspended solid (SS) from secondary rubber processing effluent (SRPE). The highest percentage removal of BOD, COD, SS, and NH3 achieved was approximately 97%, 99%, 98%, and 95%, respectively, at pH 5.0, coagulant dose of 1 g/L, coagulation time of 60 min, sedimentation time of 60 min, and at an elevated temperature of 70 °C. The best described adsorption isotherm model was found to be the Brunauer–Emmett–Teller (BET) model, indicated that the FeSO4·7H2O adsorption took placed on the surface of iron hydroxide precipitates with multilayer formation and random distribution. The kinetics analysis showed that the adsorption mechanism was well fitted with the pseudo-second-order kinetic model. The findings of the present study show that the FeSO4·7H2O waste has the potential to be used as a coagulant for the treatment of industrial effluents, including the secondary rubber processing effluent.