Stochastic theory of intramolecular vibrational energy redistribution and dissociation in the presence of radiation

1983 ◽  
Vol 79 (11) ◽  
pp. 5396-5413 ◽  
Author(s):  
Luis Alejandro Eslava ◽  
Stuart D. Augustin ◽  
Herschel Rabitz
Keyword(s):  
Vibrational Energy ◽  
Stochastic Theory ◽  
Energy Redistribution ◽  
Intramolecular Vibrational Energy Redistribution

Multiple timescales in the intramolecular vibrational energy redistribution of highly excited methanol

1995 ◽  
Vol 102 ◽  
pp. 167 ◽  
Author(s):  
Lucia Lubich ◽  
Oleg V. Boyarkin ◽  
Rebecca D. F. Settle ◽  
David S. Perry ◽  
Thomas R. Rizzo
Keyword(s):  
Vibrational Energy ◽  
Energy Redistribution ◽  
Multiple Timescales ◽  
Intramolecular Vibrational Energy Redistribution

scholarly journals Intramolecular vibrational energy redistribution and the quantum ergodicity transition: a phase space perspective

2020 ◽  
Vol 22 (20) ◽  
pp. 11139-11173 ◽  
Author(s):  
Sourav Karmakar ◽  
Srihari Keshavamurthy
Keyword(s):  
Phase Space ◽  
Energy Flow ◽  
Vibrational Energy ◽  
Energy Redistribution ◽  
Quantum Ergodicity ◽  
Connected Network ◽  
Intramolecular Vibrational Energy Redistribution ◽  
Vibrational Energy Flow ◽  
Classical Phase Space

The onset of facile intramolecular vibrational energy flow can be related to features in the connected network of anharmonic resonances in the classical phase space.

scholarly journals Direct observation of structural dynamics upon photo-excitation in a spin crossover crystal with femtosecond electron diffraction

2019 ◽  
Vol 205 ◽  
pp. 07005
Author(s):  
Yifeng Jiang ◽  
Lai Chung Liu ◽  
Henrike M. Müller-Werkmeister ◽  
Cheng Lu ◽  
Dongfang Zhang ◽  
...  
Keyword(s):  
Electron Diffraction ◽  
Structural Dynamics ◽  
Spin Crossover ◽  
Vibrational Energy ◽  
Intersystem Crossing ◽  
Structural Reorganization ◽  
Energy Redistribution ◽  
Intramolecular Vibrational Energy Redistribution ◽  
Femtosecond Electron Diffraction ◽  
Ligand Bond

Photoinduced spin transitions are studied by femtosecond electron diffraction to understand ultrafast structural dynamics associated with intersystem crossing. The results indicate the structural reorganization occurs within 2.3 ps, as the metal-ligand bond distribution narrows during intramolecular vibrational energy redistribution.

scholarly journals Suppression of Intramolecular Vibrational Energy Redistribution by Intense CW-Laser Fields

2011 ◽  
Vol 2011 ◽  
pp. 1-9 ◽  
Author(s):  
M. Sugawara
Keyword(s):  
Quantum Control ◽  
Vibrational Energy ◽  
Model System ◽  
Laser Fields ◽  
Energy Redistribution ◽  
Present Scheme ◽  
Intramolecular Vibrational Energy Redistribution ◽  
Cw Laser ◽  
Doorway State ◽  
Control Scheme

We present a quantum control scheme which realizes suppression of the intramolecular vibrational energy redistribution (IVR). In this scheme, we utilize effective decomposition brought by intense CW-laser fields, which enables to exclude the doorway state coupled to background manifolds. In doing so, we introduce a helper state and make it optically coupled with the doorway state through the intense CW-laser field. We have applied the present scheme to both the Bixon-Jortner model and the SCCl2 model system.

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